首页> 外文会议>Powder Metallurgy World Congress amp; Exhibition(Euro PM2004) vol.3: Sintered Steels; PM Tool Materials; 20041017-21; Vienna(AT) >Study of Effect of Increase of Durability of Chemical Bonding the Grains of Diamond-Like Materials, Doped Metal at Synthesis
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Study of Effect of Increase of Durability of Chemical Bonding the Grains of Diamond-Like Materials, Doped Metal at Synthesis

机译:合成类金刚石材料,掺杂金属晶粒化学键合的耐久性提高效果研究

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摘要

Experience of reception of the diamond tool in many countries shows, that at addition in a diamond-like material powder of metals the durability of coupling grains in a powder' material grows. However, the internal reasons of this effect in the published literature have not found reflection. Therefore, in the given work attempt at an electronic level is undertaken to study the given problem and whenever possible to specify optimum conditions of their synthesis. With the coherent potential method of the multiple scattering theory the electron structure of the «diamond-like material - metal» system is calculated. At doped the matrix cubic boron nitride the metal observes change of the form and energy situation of top of the valence band. The analysis of electronic structures of investigated solid solutions testifies about delocalization of resonances of condition, inherent in binary connections, that can testify to easing of chemical bonding in the specified solid solutions. Results, allowing to operate by properties of a received material at the stage of development and have significant practical interest for Powder Metallurgy, are received.
机译:在许多国家/地区接受金刚石工具的经验表明,除了金属的类金刚石材料粉末外,粉末材料中偶合晶粒的耐用性也增加了。然而,在已发表的文献中这种作用的内部原因尚未得到反映。因此,在给定的工作中,尝试在电子水平上研究给定的问题,并在可能的情况下指定其合成的最佳条件。利用多重散射理论的相干势方法,可以计算出“类金刚石材料-金属”系统的电子结构。在掺杂基体立方氮化硼时,金属观察到价带顶部的形式和能级变化。对所研究固溶体的电子结构的分析证明了二元连接中固有的条件共振的离域,这可以证明特定固溶体中化学键的松弛。收到的结果允许在开发阶段根据接收到的材料的特性进行操作,并且对粉末冶金具有重大的实际意义。

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