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Cryo-analytical electron microscopy: new insight into the understanding of crystalline and electronic structure of silver halide

机译:冷冻分析电子显微镜:对卤化银结晶和电子结构的了解新的洞察

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Recent results of structural and analytical characterization of AgX (X $EQ Br, I) microcrystals of photographic emulsions by a number of cryo-analytical electron microscopy (AEM) and image analysis techniques are presented. Monte Carlo simulations of electron beam-AgX interactions have been made for a better understanding of relationships between various signals which can be analyzed in the corresponding AEM modes. Combined cryo-ESI/EDX multielement mapping was performed on AgX grain thin sections and on tabular AgX microcrystals. The contrast imaging under filtering with selected energy windows has been applied to image the morphology, crystal and defect structures of composite tabular AgX microcrystals. Extra reflections at commensurate positions in between the main Bragg reflections and weak diffuse intensity honeycomb contours caused by twins and/or $LFBC@111$RTBC stacking faults in the shell region parallel to $LFBC@112$RTBC grain edges and polyhedral clusters of Ag$+$PLU$/ interstitials, respectively, were found in selected-area electron spectroscopic diffraction patterns. Low-loss collective excitations due to plasmons and excitons possibly superimposed with interband transitions and many- electron effects were revealed by cryo-EFTEM/EELS. The real and imaginary parts of dielectric permittivity were determined by means of a Kramers-Kronig analysis. Elemental inner shell edges of Ag and halides above 50 eV energy loss have been detected by EELS in accordance with cryo-STEM/EDX- analyses. The local crystal thickness was determined by a modified EELS log-ratio technique in agreement with measurements on grain replicas.
机译:介绍了通过许多冷冻分析电子显微镜(AEM)和图像分析技术的AGX(X $ EQ,i)噬菌体乳液微晶和图像分析的近期结果。已经进行了电子束-AGX相互作用的蒙特卡罗模拟,以便更好地理解可以在相应的AEM模式中分析的各种信号之间的关系。组合的Cryo-ESI / EDX多元素映射是在AGX晶粒薄部分和表格AGX微晶上进行的。用所选能量窗口过滤的对比度成像已经应用于图像的形态,晶体和缺陷结构的复合表格AGX微晶。由双胞胎和/或$ LFBC @ 111 $ RTBC堆叠故障与$ LFBC @ 112 $ RTBC晶粒边缘和AG的壳区域中的壳体和/或$ LFBC @ 111 $ RTBC堆叠故障造成额外的反射。分别在选定区域电子光谱衍射图案中发现$ + $ + $ /间质。由于具有间带间过渡和许多电子效应的等离子体和激子因子而导致的低损耗集体激发和Cryo-EFTEM / EFLES揭示了许多电子效果。通过kramers-kronig分析确定介电介​​电常数的真实和虚部。鳗鱼根据低温茎/ EDX分析检测到50eV能量损失以上的Ag和卤化物的元素内壳边缘。局部晶体厚度由改进的鳗鱼对数与晶粒复制品的测量结果确定。

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