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Three different types of tea as surfactant in liquid exfoliation of graphite: green tea,black tea and oolong tea

机译:三种不同类型的茶作为石墨液体去角质的表面活性剂:绿茶,红茶和乌龙茶

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Liquid phase exfoliation(LPE)with surfactant-assisted is a method to produce graph ene that used water and surfactant as solvent.Tea is one of possible surfactants that can be used in LPE of graphite as it reduced the surface tension energy of water(72.75 mJ m~(-2))to ~40-50 mJ m~(-2)which is suitable level to exfoliate graphite.Three different types of tea were used as surfactant through one-step production of graphene which were green tea(GT),black tea(BT)and oolong tea(OT).The exfoliation of graphite in each tea solutions were successful as the UV spectra of supernatant samples show peak at 270 nm which indicates the C-C bond of graphene flakes.Morphology analysis(AFM)of resulted graphene samples show that graphene sheets have sharp edges caused by sonication process.The effect of sonication time was being investigated in this work.Green tea has higher exponent factor of time(1.715)compare to black tea(1.033)and oolong tea(0.762)due to high quantity of small molecules of polyphenols present in green tea solution.Thus,it is better to used GT as surfactant in LPE of graphite compare to BT and OT.
机译:具有表面活性剂辅助的液相剥离(LPE)是制备使用水和表面活性剂作为溶剂的图形烯的方法.TEA是可用于石墨的LPE中的可能表面活性剂之一,因为它降低了水的表面张力(72.75 MJ m〜(-2))至〜40-50 mj m〜(-2),它是剥离石墨的合适水平。通过单步生产是绿茶的石墨烯的一步生产(GT ),红茶(BT)和乌龙茶(OT)。每种茶溶液中石墨的​​剥离是成功的,因为上清液样品的UV光谱显示在270nm处的峰值,表示石墨烯片的CC键。形态分析(AFM)产生的石墨烯样品表明,石墨烯片具有由超声处理引起的锋利的边缘。在这项工作中正在研究超声处理时间的效果。茶叶具有更高的指数时间因子(1.715)与红茶(1.033)和乌龙茶相比(1.715) 0.762)由于大量的多酚的多分子目前在绿茶溶液中.Thus,最好在Graphite与Bt和Ot的LPE中使用GT作为表面活性剂。

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