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Lifetime Prediction of Nano-Silica based Glass Fibre/Epoxy composite by Time Temperature Superposition Principle

机译:纳米二氧化硅基玻璃纤维/环氧复合材料的寿命预测通过时间温度叠加原理

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The incorporation of nano fillers in Fibre reinforced polymer (FRP) composites has been a source of experimentation for researchers. Addition of nano fillers has been found to improve mechanical, thermal as well as electrical properties of Glass fibre reinforced polymer (GFRP) composites. The in-plane mechanical properties of GFRP composite are mainly controlled by fibers and therefore exhibit good values. However, composite exhibits poor through-thickness properties, in which the matrix and interface are the dominant factors. Therefore, it is conducive to modify the matrix through dispersion of nano fillers. Creep is defined as the plastic deformation experienced by a material for a temperature at constant stress over a prolonged period of time. Determination of Master Curve using time-temperature superposition principle is conducive for predicting the lifetime of materials involved in naval and structural applications. This is because such materials remain in service for a prolonged time period before failure which is difficult to be kept marked. However, the failure analysis can be extrapolated from its behaviour in a shorter time at an elevated temperature as is done in master creep analysis. The present research work dealt with time-temperature analysis of 0.1% SiC2-based GFRP composites fabricated through hand-layup method. Composition of 0.1% for SiO2nano fillers with respect to the weight of the fibers was observed to provide optimized flexural properties. Time and temperature dependence of flexural properties of GFRP composites with and without nano SiO2was determined by conducting 3-point bend flexural creep tests over a range of temperature. Stepwise isothermal creep tests from room temperature (30°C) to the glass transition temperature Tg (120°C) were performed with an alternative creep/ relaxation period of 1 hour at each temperature. A constant stress of 40MPa was applied during the creep tests. The time-temperature superposition principle was followed while determining the Master Curve and cumulative damage law. The purpose of a Master Curve was to determine the variation of compliance with respect to increase in time and temperature of the specimen. The shift factors at any reference temperature were determined by Arrhenius activation energy method at a far lower temperature than Tg (Glass transition temperature) and by manual shift method at a temperature near Tg(Glass transition temperature).
机译:掺入纤维增强聚合物(FRP)复合材料中的纳米填料已经是研究人员的实验源。已发现添加纳米填料以改善玻璃纤维增​​强聚合物(GFRP)复合材料的机械,热以及电性能。 GFRP复合材料的面内机械性能主要由纤维控制,因此具有良好的值。然而,复合材料表现出差的贯穿厚度特性,其中基质和界面是显性因素。因此,它有利于通过纳米填料的分散来改变基质。蠕变被定义为在恒定胁迫下的温度经受在延长的一段时间内经过的塑性变形。使用时间温度叠加原理的母曲线测定有利于预测海军和结构应用所涉及的材料的寿命。这是因为在难以保持标记的失败之前,这种材料仍然需要长时间的时间。然而,在主蠕变分析中在升高的温度下,可以在较短的时间内从其行为外推动故障分析。通过手动铺设方法制造的0.1%SIC2的GFRP复合材料的时间 - 温度分析,对本研究工作进行了处理。观察到SiO2NANO填料相对于纤维重量的0.1%的组成,以提供优化的弯曲性能。通过在一定温度范围内进行3点弯曲弯曲蠕变试验确定GFRP复合材料弯曲性能的时间和温度依赖性。在每个温度下在替代蠕变/弛豫时间为1小时进行从室温(30℃)到玻璃化转变温度Tg(120℃)的逐步等温蠕变试验。在蠕变试验期间施加40MPa的恒定应力。遵循时间温度叠加原理,同时确定主曲线和累积损伤法。主曲线的目的是确定对样本的时间和温度的增加的依从性的变化。在比Tg(玻璃化转变温度)的温度远低于Tg(玻璃化转变温度),在Tg(玻璃化转变温度)下的温度下,通过Arhenius激活能量法测定任何参考温度的换档因子。

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