Flaky and Porous Rod-like MgO Powders Prepared by Molten Salt Synthesis

摘要

Flaky and porous rod-like MgO powders were prepared by molten salt synthesis with MgC1_2, CaCO_3, NaNO_3 and KNO_3 as raw materials. TG-DSC, XRD and SEM were used to investigate the reacion process and characterize the resulting products. The results indicated that Ca~(2+) was displaced by Mg~(2+) and dolomites were formed and finally converted into magnesium carbonates during the molten salt synthesis. Fibrous Mg(OH)_2 formed in PEG solution and flaky Mg(OH)_2 formed in EDTA-PEG solution illustrated that EDTA and PEG molecules could define the growth direction of Mg(OH)_2. The porous rod-like MgO powders with 20-80 nm in diameter and 40-100 in length-to-width ratio were obtained by the decomposition of fibrous Mg(OH)_2 at 600 °C, while the flaky MgO powders were prepared by the decomposition of flaky Mg(OH)_2 at 600 °C. Flaky MgO powders were platelike, with 30-50 nm in thickness, 200-500 nm in diameter, and up to 1.0 μm~2 in a single slice surface area.