Kinetics, Products and Mechanism of O(~3P) Atom Reactions with Alkyl Iodides

摘要

The work has shown that a very small reactor can be used with a GC system to obtain kinetic data. Using the relative kinetic technique rate coefficients have been obtained for the reaction of O(~3P) atoms with a series of alkyl iodides. Many of the rate coefficients are first time measurements. It has also been shown that alkenes and HOI are the major products of the reactions and the alkene has been quantified for the majority of the alkyl iodides studied.