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Corrosion Resistance of Alloy 2024 Anodized on Sulfuric-Citric Acid

机译:硫酸 - 柠檬酸对合金2024阳极氧化的耐腐蚀性

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Aluminium alloys are used on aerospace and automotive industry due to excellences mechanical properties. Unfortunately, aluminium alloys are susceptible to corrosion and that limit them in some corrosive environments. The aim of this work is researching the characteristics of anodized film generated with sulfuric-citric acid through to electrochemical techniques. A 2024 aluminium alloy was used as substrate employing a mixture of sulfuric and citric with a current of 0.01 and 1 A at 25°C each one for 30 minutes. Electrochemical evaluation used was cyclic potentiodynamic polarization curves (CPPC) and Electrochemical Impedance Spectroscopy (EIS) in 3.5% NaCl. Scanning Electron Microscopy (SEM) was used to determinate morphology and thickness of coating. Results shows that aluminium anodized with sulfuric-citric acid mixture presenting less pitting corrosion resistance without present a significative difference in surface morphology.
机译:由于卓越的机械性能,铝合金用于航空航天和汽车工业。不幸的是,铝合金易受腐蚀性,并限制在一些腐蚀性环境中。这项工作的目的正在研究用硫酸柠檬酸产生的阳极氧化膜的特性通过电化学技术。使用2024铝合金作为采用硫酸和柠檬酸混合物的基材,其电流为0.01和1A,每一个持续30分钟。使用的电化学评估是3.5%NaCl中的循环电位偏振曲线(CPPC)和电化学阻抗光谱(EIS)。扫描电子显微镜(SEM)用于确定涂层的形态和厚度。结果表明,铝阳极氧化用硫酸柠檬酸混合物呈现较少的耐腐蚀性而不存在表面形态的显着差异。

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