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Influence of process parameters on the properties of TEOS–PECVD-grown SiO2 films

机译:过程参数对Teos-PECVD生长SiO2膜性能的影响

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The influence of chamber pressure, substrate temperature and mass flow ratio on growth rate, refractive index and stress of plasmaenhanced chemical vapor deposition (PECVD) grown SiO2 films has been investigated. In this study, the silicon dioxide films were grown by homemade PECVD system by carrying three different sets of processes for variation in chamber pressure (70–240 Pa), substrate temperature in the range of 523–673 K and flow rate ratio (O2/TEOS) of 2–10. In these processes, liquid tetraethoxysilane (TEOS) has been used as a source of Si instead of SiH4 to avoid difficult handling of SiH4. The growth rate (by measuring thickness for specified time process), refractive index and stress of the deposited SiO2 films have been determined by ellipsometry technique. The present study reveals that, in order to grow good quality SiO2 films for their microelectronics applications, where stress is of prime importance, deposition processes of TEOS–PECVD should be carried out with substrate temperature and flow ratio variations. However, for optoelectronics applications, the growth processes carried out with varying chamber pressure are believed to be highly desirable, they allow precise control of the refractive index and a higher thickness.
机译:研究了腔室压力,衬底温度和质量流量比对增殖速率,折射率和沉积的化学气相沉积(PECVD)生长的SiO 2膜的生长速率,折射率和应力的影响。在该研究中,通过携带三组不同的方法来通过自制PECVD系统生长二氧化硅膜,用于腔室压力(70-240Pa)的变化,底物温度为523-673k和流速比(O2 / TEOS)2-10。在这些方法中,液体四乙氧基硅烷(TEOS)已被用作Si的源代替SiH4,以避免SiH4的困难处理。通过椭圆形技术确定生长速率(通过测量指定时间过程的厚度),沉积的SiO 2膜的折射率和应力。本研究揭示了,为了为其微电子应用增长良好的SiO2薄膜,其中应力是主要的重要性,TEOS-PECVD的沉积过程应具有基板温度和流量比变化。然而,对于光电子应用,认为具有不同室压力的生长过程是非常理想的,它们允许精确地控制折射率和更高的厚度。

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