Hydroformylation of 1-Octene in SCCO2 with Rh Catalyst in the Presence of non Fluorinated Ligands

机译：在非氟化配体存在下用RH催化剂的SCCO 2中1-辛烯的加氢甲酰化

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

In the present work a commercial catalyst (Rh(CO)2(acac)) has been used for the hydroformylation of 1 -octene in scCC^ in the presence of non-fluorinated ligands added to improve the selectivity and the normal :iso ratio for aldehydes Diphenyl-pam-tertbutylbiphenylphosphine (TFFPF2) both nude and included inside triacetyl-/?-cyclodextrin was used. Both these compounds have been found to be fairly soluble in SCCO2 The effects of ligands on the performances of the catalytic system have been investigated and preliminary results will be presented.

机译：在本作品中，商业催化剂（RH（CO）2（ACAC））已被用于SCCC中的1-酸乙酯的加氢甲酰化，在添加的非氟化配体中加入以改善选择性和正常：ISO比率使用醛二苯基-PAM-叔丁基苯并苯基膦（TFFPF2）裸体和包括在三乙酰基 - /α - 环糊精内。已经发现这两种化合物都是相当溶于SCCO2，配体对催化体系的性能的影响已经研究，并提出了初步结果。

著录项

来源
《Conference on Supercritical Fluids and Their Applications》|2006年||共4页
会议地点
作者
G Filardo; A Cipollina; A. Galiaa; E. Monflierb; O Scialdonea; A. Visigoti;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类 TQ02-532;
关键词

相似文献

外文文献
中文文献
专利

1. Kinetics of Hydroformylation of 1-Octene Using [Rh(COD)Cl]_2-TPPTS Complex Catalyst in a Two-Phase System in the Presence of a Cosolvent [J] . R. M. Deshpande, Purwanto, H. Delmas, Industrial & Engineering Chemistry Research . 1996,第11期

机译：[Rh（COD）Cl] _2-TPPTS络合催化剂在两相体系中共溶剂存在下1-辛烯的加氢甲酰化动力学
2. Novel alpha-fluorinated cyclic phosphite and phosphinite ligands and their Rh-complexes as suitable catalysts in hydroformylation [J] . Odinets R, Kegl T, Sharova E, Journal of Organometallic Chemistry . 2005,第14期

机译：新型α-氟化环状亚磷酸酯和次膦酸酯配体及其Rh络合物作为加氢甲酰化反应的合适催化剂
3. Preparation of porous ruthenium catalysts utilizing a silsesquioxane ligand;catalytic activity towards hydroformylation of 1-octene [J] . Kenji Wada, Ryuta Tomoyose, Teruyuki Kondo Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2009,第1期

机译：利用倍半硅氧烷配体制备多孔钌催化剂;对1-辛烯加氢甲酰化的催化活性
4. Hydroformylation of 1-Octene in SCCO2 with Rh Catalyst in the Presence of non Fluorinated Ligands [C] . G Filardo, A Cipollina, A. Galiaa, Conference on Supercritical Fluids and Their Applications . 2006

机译：在非氟化配体存在下用RH催化剂的SCCO 2中1-辛烯的加氢甲酰化
5. Implementation of Asymmetric Hydroformylation with Rhodium Bisdiazaphos Catalysts: AHF in Flow and Rh-Catalyzed Hydroacylation [D] . Jones, Bradley R. 2017

机译：双重氮铑铑催化剂实现不对称加氢甲酰化：AHF流动和Rh催化加氢酰化
6. Synthesis of Nixantphos Core-Functionalized Amphiphilic Nanoreactors and Application to Rhodium-Catalyzed Aqueous Biphasic 1-Octene Hydroformylation [O] . Ahmad Joumaa, Florence Gayet, Eduardo J. Garcia-Suarez, 2020

机译：Nixantphos核心功能性两亲纳米反应器的合成及其在铑催化的双相1-辛烯加氢甲酰化反应中的应用
7. Kinetics of hydroformylation of 1-octene in ionic liquid-organic biphasic media using rhodium sulfoxantphos catalystud [O] . Deshpande Raj M., Kelkar Ashutosh A., Sharma Amit, 2011

机译：铑硫氧黄磷催化剂在离子液体-有机双相介质中1-辛烯的加氢甲酰化动力学 ud
8. Rhenium Catalysis:Ⅰ. Hydrogenation and Hydroformylation Using Rhenium Carbonyl Compounds. Ⅱ. Hydrogenation Using Catalysts Obtained from the Reduction of Perrhenates with Metals in Aqueous Solution [R] . T. G. Selin 1957

机译：铼催化：Ⅰ。使用铼羰基化合物进行氢化和加氢甲酰化。 Ⅱ。在水溶液中用金属还原高铼酸盐获得催化剂的氢化

Hydroformylation of 1-Octene in SCCO2 with Rh Catalyst in the Presence of non Fluorinated Ligands

摘要

著录项

相似文献

相关主题

期刊订阅