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CVD OF MOLECULE-BASED CONDUCTORS AND MAGNETS

机译:基于分子的导体和磁铁的CVD

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Thin films of the molecular conductor TTF-TCNQ, and of two molecular magnets (Cp~*_2Fe~(+))(TCNE~-) and V(TCNE)_x were grown by chemical vapor deposition. In the case of TTF-TCNQ the deposition was carried out on Si and stainless steel conversion coatings (SSCC) surfaces. The high adsorption properties of SSCC surfaces, due to their fractal-like morphology, increases the surface coverage vs. that observed on Si substrates. (Cp~*_2Fe~+)(TCNE~-) and V(TCNE)_x were deposited on KBr pellets. They exhibit field dependent magnetization below 3.7 K and at room temperature, respectively. Slight differences are observed in the ordering temperature T_c of (Cp~*_2Fe~+ )(TCNE~-) and B_s value of V(TCNE)_x vs. those of the parent compounds. This reflect a specific structural organization of the compound on the substrate surface directly connected to the film formation process.
机译:通过化学气相沉积生长分子导体TTF-TCNQ的薄膜和两个分子磁体(CP〜* _2Fe〜(+))(TCNE〜 - )和V(TCNE)_X。在TTF-TCNQ的情况下,在Si和不锈钢转换涂层(SSCC)表面上进行沉积。由于它们的分形形态,SSCC表面的高吸附性能增加了在Si衬底上观察到的表面覆盖率对。 (CP〜* _2FE〜+)(TCNE〜 - )和V(TCNE)_x沉积在KBR颗粒上。它们分别在3.7 k和室温下表现出现场依赖性磁化。在(CP〜* _2Fe〜+)(TCNE〜 - )和V(TCNE)_X与母体化合物的v(TCNE〜 - )和B_S值的顺序温度T_C中观察到轻微差异。这反射了直接连接到膜形成过程的基板表面上的化合物的特定结构组织。

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