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Obtainment of Chelating Agents Through the Enzymatic Oxidation of Lignins by Phenol Oxidase

机译:通过苯酚氧化酶通过酶促氧化通过酶促氧化螯合剂

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Oxidation of lignin obtained from acetosolv and ethanol/water pulping of sugarcane bagasse was performed by phenol oxidases: tyrosinase (TYR) and laccase (LAC), to increase the number of carbonyl and hydroxyl groups in lignin, and to improve its chelating capacity. The chelating properties of the original and oxidized lignins were compared by monitoring the amount of Cu~(2+) bound to lignin by gel permeation chromatography. The Acetosolv lignin oxidized with TYR was 16.8% and with LAC 21% higher than that of the original lignin. For ethanol/water lignin oxidized with TYR was 17.2% and with LAC 18% higher than that of the original lignin.
机译:通过苯酚氧化酶:酪氨酸酶(Tyr)和漆酶(LAC)进行甘蔗果糖甘蔗蛋白的木质素氧化,以增加木质素中羰基和羟基的数量,提高其螯合能力。通过凝胶渗透色谱法监测与木质素结合的Cu〜(2+)的量进行比较原始和氧化木质素的螯合性质。用TYR氧化的乙酰肌醇醇为16.8%,并且LAC比原始木质素高21%。对于用TYR氧化的乙醇/水木质素为17.2%,并且LAC比原始木质素高18%。

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