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Effect of Al and N doping on structural and optical properties of sol-gel derived ZnO thin films

机译:Al和N掺杂对溶胶-凝胶衍生ZnO薄膜结构和光学性能的影响

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In this work, ZnO, N-doped ZnO(NZO), Al-doped ZnO(AZO) and Al, N-doped ZnO(ANZO) thin films were prepared by the sol-gel spin-coating method based on zinc acetate dihydrate(CH3COO)2Zn·2H2O, Aluminium acetate (C4H7AlO5), Ammonium acetate(CH3COONH4), absolute ethanol (C2H5OH) and diethanolamine ((HOCH2CH2)2NH, DEA). All films were spin-coated on borosilicate substate for several coating repetition followed by annealing process at 550 °C for 4 hr in air. The structural properties and surface morphologies of films were characterized by X-ray diffraction (XRD) and Field Emission Scanning Electron Microscope (FE-SEM). The optical properties of the films were interpreted from their transmission spectra using UV-VIS spectrophotometer.
机译:在这项工作中,基于二水合醋酸锌的溶胶-凝胶旋涂法制备了ZnO,N掺杂的ZnO(NZO),Al掺杂的ZnO(AZO)和Al,N掺杂的ZnO(ANZO)薄膜。 CH 3 COO) 2 Zn·2H 2 O,乙酸铝(C 4 H 7 < / inf> AlO 5 ),乙酸铵(CH 3 COONH 4 ),无水乙醇(C 2 H 5 OH)和二乙醇胺((HOCH 2 CH 2 2 NH,DEA)。将所有膜旋涂在硼硅酸盐亚状态上重复几次涂覆,然后在空气中于550°C退火4小时。利用X射线衍射(XRD)和场发射扫描电子显微镜(FE-SEM)对薄膜的结构特性和表面形貌进行表征。使用UV-VIS分光光度计从它们的透射光谱来解释膜的光学性质。

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