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Effect of A1 and N doping on structural and optical properties of sol-gel derived ZnO thin films

机译:Al和N掺杂对溶胶-凝胶法制备ZnO薄膜结构和光学性能的影响

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摘要

In this work, the preparation of ZnO, N-doped ZnO (NZO), Al-doped ZnO (AZO) and Al, N-doped ZnO (ANZO) thin films by the sol-gel spin-coating method is reported. The structural properties and surface morphologies of films were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). The optical properties of the films were interpreted from their transmission spectra using UV-VIS spectrophotometer. The XRD and SEM results disclosed that the crystallization quality and grain size of as-prepared films were highly influenced by N and Al doping. UV-VIS spectrophotometer results indicated that Al and N additives could significantly enhance the optical transparency and induce the blue-shift in optical bandgap of ZnO films.
机译:在这项工作中,报道了通过溶胶-凝胶旋涂法制备ZnO,N掺杂的ZnO(NZO),Al掺杂的ZnO(AZO)和Al,N掺杂的ZnO(ANZO)薄膜。用X射线衍射(XRD)和场发射扫描电子显微镜(FE-SEM)对薄膜的结构性能和表面形貌进行表征。使用UV-VIS分光光度计从它们的透射光谱来解释膜的光学性质。 XRD和SEM结果表明,制备的薄膜的结晶质量和晶粒尺寸受N和Al掺杂的影响很大。 UV-VIS分光光度计的结果表明,Al和N添加剂可以显着提高光学透明性,并引起ZnO薄膜的光学带隙发生蓝移。

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