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PRECURSOR FOR FORMATION OF THIN FILM, PREPARATION METHOD THEREFOR, AND METHOD FOR FORMING THIN FILM COMPRISING SAME

机译:形成薄膜的前体,其制备方法及其形成薄膜的方法

摘要

The present invention relates to a precursor for the formation of a thin film, a preparation method therefor, and a method for forming a thin film comprising same and, more specifically, to a precursor for the formation of a thin film, a preparation method therefor, and a method for forming a thin film comprising same, wherein the precursor is a liquid under conditions of 20℃ and 1 bar and comprises 20 to 100 wt% of a coordination compound and 0 to 80 wt% of an alkyl cyanide with an alkyl having 1 to 15 carbon atoms, the coordination compound being represented by chemical formula 1 below: [chemical formula 1] MXnLmYz (M is niobium (Nb), tungsten (W), or molybdenum (Mo); X is a halogen element; n is an integer of 1 to 6; L is an alkyl cyanide with an alkyl having 1 to 15 carbon atoms or a linear or cyclic saturated hydrocarbon having 3 to 15 carbon atoms and being substituted with at least one nitrogen (N), oxygen (O), phosphorus (P), or sulfur (S); m is an integer of 1 to 3; Y that is bound is an amine; z is an integer of 0 to 4; and n+z is an integer of 3 to 6). According to the present invention, there is an effect of providing a precursor for the formation of a thin film, a preparation method therefor, and a method for forming a thin film comprising same, wherein the precursor is in a liquid state at room temperature and is highly volatile and thus shows a very high deposition rate and is easy to handle when injected into a thin film deposition chamber, and especially, the precursor has excellent thermal stability and thus enables the formation of a thin film with high purity and excellent step coverage.
机译:本发明涉及用于形成薄膜的前体,其制备方法,以及用于形成包含该薄膜的方法,更具体地,以形成薄膜的前体,制备方法和形成该薄膜的方法,其中前体是在20℃和1巴的条件下的液体,并包含20至100wt%的配位化合物和0至80重量%的烷基氰化物用烷基具有1至15个碳原子,由下面的化学式1表示的配位化合物:[化学式1] MXNLMYZ(M是铌(Nb),钨(W)或钼(Mo); x是卤素元素;ñ是1至6的整数; L是氰化物,其具有具有1至15个碳原子的烷基或具有3至15个碳原子的线性或环状饱和烃,并且被至少一种氮气(n),氧气(O. ),磷(p)或硫; m是1至3的整数; y是绑定是胺; z是0到4的整数; n + z是3到6的整数。根据本发明,提供用于形成薄膜的前体,其制备方法以及用于形成包含其的薄膜的方法,其中前体在室温下处于液态状态和是高挥发性的,因此显示出非常高的沉积速率并且在注入薄膜沉积室时易于处理,特别是,前体具有优异的热稳定性,因此能够形成具有高纯度和优异步骤覆盖的薄膜。

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