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Coating composition for coating particles, positive electrode, negative electrode, all-solid-state battery, and sulfide-based all-solid-state battery

机译:用于涂布颗粒,正极,负极,全固态电池和基于硫化物的全固态电池的涂料组合物

摘要

Provided are sulfide-based particles which not only hardly generate hydrogen sulfide when exposed to the atmosphere but also have excellent ionic conductivity and dispersibility in a solvent. The surface of the sulfide-based particles is coated particles coated with a fluorine-containing polymer, and the fluorine-containing polymer is the formula (1) (in the formula, X is a hydrogen atom or the like, Y is a direct bond or the like. Rf is a structural unit (1) based on the monomer (1) represented by a linear or branched fluoroalkyl group having 1 to 10 carbon atoms, and the formula (2) (in the formula). , R1 is a hydrogen atom or the like, and R2 is a sulfur having 1 or more carbon atoms which may contain at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom and a sulfur atom in the structure. It is a hydrogen group. However, when R1 is H or CH3, R2 has 3 carbon atoms containing at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom, and a sulfur atom in the structure. A structural unit (2) based on at least one selected from the group consisting of a monomer (2) represented by the above-mentioned hydrocarbon group or a hydrocarbon group having 6 or more carbon atoms having a ring structure) and the like. It is a coating particle characterized by containing and. [Chemical 1] [Chemical 2]
机译:提供的是硫化物的颗粒,其在暴露于大气时不仅在硫化物中难以产生硫化氢,而且在溶剂中具有优异的离子电导率和分散性。硫化物基颗粒的表面被涂有含氟聚合物的涂覆颗粒,含氟聚合物是式(1)(在式中,X是氢原子等,Y是直接键等等。RF是基于由具有1至10个碳原子的线性或支链氟代烷基表示的单体(1),以及式(2)(在式中)。,R1是a氢原子等,R2是具有1或更多个碳原子的硫,其可含有至少一种选自氧原子,氮原子和结构中的硫原子的原子。它是氢基团。然而,当R1是H或CH3时,R 2具有3个碳原子,其含有至少一种选自氧原子,氮原子和结构中的硫原子的原子。结构单元(2)基于选自由上述烃代表的单体(2)中选出的至少一种基团或烃基具有具有环结构的6或更多个碳原子的碳原子。它是含有和的涂料颗粒。 [化学1] [化学2]

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