首页> 外国专利> Procedure for the preparation of chloroacetanilidas sililadas. (Machine-translation by Google Translate, not legally binding)

Procedure for the preparation of chloroacetanilidas sililadas. (Machine-translation by Google Translate, not legally binding)

机译:制备氯乙酰苯胺甲硅烷的程序。 (通过Google翻译进行机器翻译,没有法律约束力)

摘要

Procedure for the preparation of silylated chloroacetanility, of formula I **(See formula)** in which R means a lower alkyl group with at most 4 carbon atoms, a -CH2-OH2-Si (CH3) 3 group, a -CH2-Si (CE3) 3 group or a trimethylsilyl group, Z means a straight or branched alkylene chain, with at most 3 C atoms, R'means halogen, alkyl or lower alkoxy with 3 atoms from 0 at most or trimethylsilyl and n means the number 0 or 1, that constitute the active matter in the composition of agents to influence the growth of plants and especially to combat weeds, by application before their emergence, in the cultivation of useful plants characterized by reacting a substituted aniline of formula IX **(See formula)** with an aldehyde or a cup of formula III **(See formula)** to form a Schiff base of formula IV **(See formula)** then add to the double bond a chloroacetyl halide **(See formula)** with formation of a product of formula V **(See formula)** and then reacted with an alcohol of the formula HO-R, in the presence of a base, to form the final product of the formula I; in whose above formulas, Hal means a halogen atom, preferably chlorine or bromine, and D and E each signify hydrogen or monovalent aliphatic hydrocarbon radicals which together with the C atom to which they are attached constitute the radical -Z-OR, while Z, R, R'and n have the same meaning as in formula I. (Machine-translation by Google Translate, not legally binding)
机译:式I **(参见式)**的甲硅烷基化氯乙酸的制备方法,其中R表示具有至多4个碳原子的低级烷基,-CH 2 -OH 2 -Si(CH 3)3基团,-CH 2 -Si(CE3)3基或三甲基甲硅烷基,Z表示具有最多3个C原子的直链或支链亚烷基链,R'表示卤素,烷基或具有最多0个碳原子的3个原子的烷基或低级烷氧基或三甲基甲硅烷基,n表示编号0或1,它们构成了成分组成中的活性物质,可通过在植物出苗前施用而影响植物的生长,尤其是与杂草进行战斗,以特征在于式IX的取代苯胺反应的有用植物的培养(参见式)**与醛或杯式III **(参见式)**形成式IV的席夫碱**(参见式)**然后在双键中添加氯乙酰基卤化物** (参见式)**,形成式V的产物**(参见式)**,然后与式HO的醇反应-R,在碱的存在下,形成式I的最终产物;在其上式中,Hal表示卤素原子,优选为氯或溴,并且D和E各自表示氢或与它们所连接的C原子一起构成-Z-OR基团的一价脂族烃基。 R,R'和n具有与式I相同的含义。(通过Google翻译进行机器翻译,没有法律约束力)

著录项

  • 公开/公告号ES439458A1

    专利类型

  • 公开/公告日1977-02-16

    原文格式PDF

  • 申请/专利权人 CIBA-GEIGY A. G.;

    申请/专利号ES19750439458

  • 发明设计人

    申请日1975-07-16

  • 分类号C07F;A01N;

  • 国家 ES

  • 入库时间 2022-08-23 00:29:57

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