method for separating isoprene from c5 hydrocarbon mixtures containing isoprene.

摘要

1417733 Distilling hydrocarbons SNAMPROGETTI SpA 26 Jan 1973 [28 Jan 1972] 4244/73 Heading C5E Isoprene is separated from a C 5 cut, e.g. from steam-cracking, by (a) rectifying (at 17) to take overhead (3) C 4 hydrocarbons, low-boiling acetylenes and the greater part of the isopentane, to take off as bottoms (4) any polymers and part of the high-boiling hydrocarbons, and leave a side-stream (5) of impure isoprene; (b) subjecting this stream to an extractive distallation (26) with a solvent comprising a polar organic compound and water to take overhead (27) isoprene together with acrylic C 5 olefines, cyclopentene, normal pentane and the remainder of the isopentane, to take off as bottoms (28) solvent, and leave a side-stream (29) of cyclopentadiene monomer and other hydrocarbons soluble in the solvent; (c) subjecting the overhead (27) to a second extractive distillation (21) to take overhead (11) acyclic olefines, normal pentane and isopentane, and as bottoms (12) isoprene, cyclopentene and solvent; (d) flashing this bottoms stream (at 22) to give an isoprene stream (13) and a stream (24) comprising the solvent with enough isoprene to serve as reflux in the first extractive distillation, (e) rectifying the stream (13) of isoprene from the flash evaporator to take off as bottoms (15) the heavy hydrocarbons still remaining, as overhead (14) a stream of isoprene with traces of low-boiling hydrocarbons, which is recycled to the first rectification, and as a sidestream (16) isoprene of polymerization quality; and (f) recycling to the first extractive distillation (26) the bottoms from the flash evaporator. As shown, the solvent from the bottom of column 26 is that supplied to the top of column 21, by line 28. In a modification (Fig. 1, not shown), only two streams are taken off from the first extractive distillation, the bottoms comprise solvent, cyclopentadiene monomer and highboiling acetylenes, and are stripped, the solvent going to the second extractive distillation, and the hydrocarbons to a rectifying column (20) where a bottoms comprising cyclopentadiene monomer, high-boiling acetylenes and a large proportion of dienes other than isoprene is discarded (8), and an overhead stream (9) of isoprene is recycled to the first rectification. Polar organic compounds suitable for use in the solvent are N-formylmorpholine, morpholine, aniline, acetonitrile, furfural, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, beta-methoxy-propionitrile, and mixtures of these with one another. Reference has been directed by the Comptroller to Specification 1,283,519.