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Process for recovering and reactivating catalysts that contain cobalt used in the conversion of olefins with carbon monoxide and alkanols

机译:回收和再活化含钴催化剂的方法,该催化剂用于烯烃与一氧化碳和链烷醇的转化

摘要

A process for recovering and reactivating at derUmsetzung of olefins with carbon monoxide and alkanols inserted catalysts consisting of a cobalt compound and pyridine and / or a non-ortho substituted alkylpyridine as promoter, which comprises treating the reaction mixture with an oxygen containing gas, the unreacted alkanol and olefin, promoter and the reaction products removed by distillation, to receive the thereby resulting distillation residue in pyridine and / or a non-ortho-substituted alkylpyridine and treats the suspension thus obtained with a mixture of carbon monoxide and hydrogen at a temperature of 100 to 250 ° C and a pressure of at least 50 bar.
机译:一种用一氧化碳和链烷醇插入的由钴化合物和吡啶和/或非邻位取代的烷基吡啶作为促进剂的催化剂在烯烃的去甲基上回收和再活化的方法,该方法包括用未反应的含氧气体处理反应混合物。通过蒸馏除去链烷醇和烯烃,促进剂和反应产物,从而在吡啶和/或非邻位取代的烷基吡啶中接收由此形成的蒸馏残余物,并在温度为190℃下用一氧化碳和氢气的混合物处理由此获得的悬浮液。 100至250°C,压力至少50 bar。

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