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PRODUCTION AND USE OF ZINC-CONTAINING ALUMINUM SILICATE CATALYSTS

机译:含锌铝硅酸盐催化剂的生产和使用

摘要

Zinc-containing aluminium silicate catalysts are obtainable by exposing amorphous aluminium silicate or mixtures, from which such an aluminium silicate is obtainable, with aliphatic C2- to C24-amines and/or cycloaliphatic C4- to C24-amines and/or ammonium salts of these amines and/or quaternary ammonium compounds obtainable from these amines by quaternisation and with zinc compounds which are soluble or partially soluble in aqueous alkali solutions, in an aqueous medium at a pH greater than 8 to temperatures from 50 to 250 DEG C, then washing them out, drying and calcining at 300 to 600 DEG C, and the preparation thereof and the use thereof for converting lower alcohols and/or ethers to hydrocarbons.
机译:含锌的硅酸铝催化剂可通过将无定形硅酸铝或其混合物与脂肪族的C2至C24胺和/或脂环式C4至C24胺和/或它们的铵盐暴露而获得,从中可获得这种硅酸铝。在pH大于8的水性介质中,温度为50至250℃的条件下,可通过季铵化并与可溶于或部分溶于碱水溶液的锌化合物一起从这些胺中获得的胺和/或季铵化合物,然后将其洗涤在300-600℃下干燥,煅烧,及其制备方法及其在将低级醇和/或醚转化为烃中的用途。

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