METHOD FOR DEPOSITING METALS ON ELECTRICALLY CONDUCTIVE, POLYMERIC CARRIERS AND USE OF THE MATERIALS RECEIVED IN ELECTRICAL TECHNOLOGY, FOR THE ANTISTATIC EQUIPMENT OF PLASTICS AND AS HETEROGENEOUS CATALYSTS

摘要

A process for depositing metals onto electrically conductive, polymeric carriers, wherein a finely divided metal M having a standard potential Eo of -2 V is deposited, from a solution of a metal cation compound of the formula (I) Ml'Lm1Ln2Lo3Lp4 (I) where M', L1, L2, L3, L4, l, m, n, o, and p are as defined in the claims, in an aprotic polar or non-polar solvent, onto a polymeric, electrically conductive carrier of the formula (II) [My''(P)]x (II) where M'' is Li, Na, K, Rb or Cs, P is P=-CH-, -C6H4-, -C4H2S-, -C6H4S-, -C4H2O-, -C4H2NH- -C6H4O- or -C5H3N- y is from 0.001 to 0.6 and x is from 5 to 1,000, or onto a polymeric, electrically conductive carrier of the formula (III) [(P)(X)y]x (III) where P is one of the groups listed for formula (II), X is ClO4(-), AsF6(-), PF6(-), SbF6(-), BF4(-), HSO4(-), CF3SO3(-) or Br(-), y is from 0.001 to 0.6 and x is from 5 to 1,000, by reduction, preferably at from -100 DEG to +100 DEG C. The electrically conductive, polymeric systems can be employed in the electrical industry for the production of solar cells, for converting and fixing radiation, and for the production of electric and magnetic switches and electrical storage devices, and can also be used as heterogeneous catalysts and to provide an antistatic finish on plastics.