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LOW-TEMPERATURE FLUIDITY IMPROVER FOR FUEL OIL AND FUEL OIL HAVING LOW-TEMPERATURE FLUIDITY

机译:燃油和具有低温流动性的燃油的低温流动性赋予

摘要

PURPOSE:To provide the titled improver having excellent wax-dispersibility, consisting of a half amide or half ester of an unsaturated sulfonic acid anhydride adduct of an ethylene/vinyl carboxylate copolymer or its amine salt. CONSTITUTION:An unsaturated carboxylic acid anhydride adduct (A) of an ethylene/vinyl carboxylate copolymer having a number-average MW of 1,000- 10,000 and an ethylene content of 20-85wt% [unsaturated carboxylic acid anhydride/vinyl carboxylate = 0.05-1.0 (molar ratio)] is reacted with a 10-22C prim. or sec. amine or an 8-22C straight-chain aliph. alcohol at 80-40 deg.C in the absence of a catalyst to obtain the titled improver composed of a half amide (amine salt) of component A contg. a residue of a half amide of succinic acid of formula I (wherein R2 is a 10-22C alkyl; R1 is H, R2; X is H, an alkylammonium derived from a 10-22C prim. or sec. alkylamine) or a half ester of component A contg. a residue of a half ester of succinic acid of formula II (wherein R is a 8-22C alkyl).
机译:用途:提供具有优异的蜡分散性的标题改进剂,它由乙烯/乙烯基羧酸酯共聚物或其胺盐的不饱和磺酸酐加合物的半酰胺或半酯组成。组成:乙烯/乙烯基羧酸酯共聚物的不饱和羧酸酐加合物(A),数均分子量为1,000-10,000,乙烯含量为20-85wt%[不饱和羧酸酐/乙烯基羧酸酯= 0.05-1.0(摩尔比)与10-22℃的伯反应。或秒胺或8-22C直链烯烃。在80-40℃下,在没有催化剂的情况下,用乙醇制备得到标题的由组分A的半酰胺(胺盐)组成的改进剂。式I的琥珀酸半酰胺的残基(其中R2是10-22C烷基; R1是H,R2; X是H,衍生自10-22C伯或仲烷基胺的烷基铵)或一半组分A的酯续式II的琥珀酸半酯的残基(其中R是8-22C烷基)。

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