A membrane for selectively separating gases having high and selective permeability for oxygen and sufficient strength which is capable of extracting and concentrating oxygen in a mixed gases, especially in the air, and is produced from a novel poly(disubstituted acetylene) /polyorganosiloxane graft copolymer where the main chain is composed of poly(disubstituted acetylene) and the side chain is composed of polyorganosiloxane, and the copolymer.
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