首页> 外国专利> process for extraction of alumina from bauxite by the bayerverfahren monohydrate enthaltendem.

process for extraction of alumina from bauxite by the bayerverfahren monohydrate enthaltendem.

机译:Bayerverfahren一水合物焓从铝土矿中提取氧化铝的方法。

摘要

A process for the continuous production of alumina by means of the Bayer process by alkaline attack in reactors on bauxites which primarily consist of aluminum monohydrates and contain silica in a free state or combined in the form of aluminum silicate, the essential aim of which is to delay scaling of the reactors by deposits of sodium silico-aluminate on the reactor walls. The process comprises the following steps: (1) the bauxite is put into suspension by crushing in a sodic liquor (aqueous solution of caustic soda); (2) the suspension is raised to a temperature of from 90 DEG to 108 DEG C. and held at that temperature for a period of time sufficient to convert at least 75% of the aluminum silicate contained in the bauxite into insoluble sodium silico-aluminate; (3) The suspension is then subjected to steam heating by passing through a tube-type heat exchanger under pressure at a temperature which is at least equal to 160 DEG C. and preferably is from 160 DEG to 230 DEG C., with a speed of rise in temperature of from 2 DEG to 12 DEG C./minute and with a speed of flow in the tubular reactor of from 0.4 to 7 meters per second; (4) by heat exchange with a heat exchange fluid in a tubular reactor, the suspension is raised to a temperature of from 200 DEG to 300 DEG C. and preferably from 230 DEG to 290 DEG C. and maintained at that temperature so as to solubilize at least 90% of the extractible alumina; and (5) the suspension is returned to atmospheric pressure by successive expansion operations, with recovery of the steam.
机译:一种通过拜耳法连续生产氧化铝的方法,该方法是在反应器中对铝土矿进行碱侵蚀,该铝土矿主要由一水合铝组成,并以游离态包含二氧化硅或以硅酸铝形式结合,其基本目的是:通过在反应器壁上沉积硅铝酸钠来延迟反应器的结垢。该方法包括以下步骤:(1)通过在苏打液(苛性苏打水溶液)中压碎使铝土矿悬浮。 (2)将悬浮液升温至90-108℃,并在该温度下保持足够长的时间,以使铝土矿中至少75%的硅酸铝转化成不溶的硅铝酸钠。 ; (3)然后使悬浮液在压力下至少在160℃,最好在160℃至230℃的温度下通过管式热交换器进行蒸汽加热。温度以每秒2至12℃的速度上升,并且在管式反应器中的流速为每秒0.4至7米; (4)通过在管式反应器中与热交换流体进行热交换,将悬浮液升温至200-300℃,优选230-290℃,并保持在该温度下。溶解至少90%的可萃取氧化铝; (5)通过连续的膨胀操作使悬浮液恢复到大气压,并回收蒸汽。

著录项

相似文献

  • 专利
  • 外文文献
  • 中文文献
获取专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号