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Deposition process in the vapour phase at low temperature of a ceramic coating of the metallic nitride or carbonitride type

机译:金属氮化物或碳氮化物类型的陶瓷涂层在低温下的气相沉积工艺

摘要

The object of the invention is a one-step deposition process of a coating of the ceramic type based on nitrides or carbonitrides of at least one metallic element selected from Cr, V, Zr, W, Mo, Co, Mn, Ni, Hf and Ta on a metallic or ceramic substrate, massive or obtained from fibres, by deposition in the vapor phase wherein a coating is deposited on the substrate by a chemical means at a pressure lower than 10 kPa at a temperature lower than 600 C. and by using a system of precursors constituted simultaneously of:PPan organo-metallic precursor of the said metallic element selected from the organo-metallic compounds of the sandwich type of general formula:PP[Ar. sup.1 M Ar.sup.2.sub.n ]L.sub.x L'.sub.yPPa nitrogen precursor selected from ammonia and hydrazine.
机译:发明内容本发明的目的是一种基于至少一种选自Cr,V,Zr,W,Mo,Co,Mn,Ni,Hf和H的金属元素的氮化物或碳氮化物的陶瓷类型涂层的一步沉积工艺。通过在气相中沉积而在金属或陶瓷基质上的Ta,该基质是大块的或由纤维制得的,其中通过化学方法在低于10 kPa的压力下于低于600 C的温度下通过化学方法在该基质上沉积涂层,并通过使用一种同时由以下组成的前体系统:P所述金属元素的有机金属前体,该金属元素选自通式为P P的夹心型有机金属化合物。 sup.1 M Ar.n.L.sub.L′y P选自氮和肼的氮前体。

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