首页> 外国专利> Modified alkyl! resins for paint compsns. having low yellowing - comprise esterified mixt. of fatty acids and/or oils, carboxylic acids, poly:ol(s), poly:carboxylic acids (anhydride) etc.

Modified alkyl! resins for paint compsns. having low yellowing - comprise esterified mixt. of fatty acids and/or oils, carboxylic acids, poly:ol(s), poly:carboxylic acids (anhydride) etc.

机译:改性烷基!涂料组合物用树脂。低黄变-包括酯化混合物。脂肪酸和/或油,羧酸,多元醇,多元羧酸(酸酐)等。

摘要

The modified alkyd resins comprise a mixt. of compsns. (A) and (B) where (A) comprises 60-80 wt.% of dried fatty acids and/or oils having an iodine number of at least 110 pref. 130-170, up to 10 wt.% of aromatic- and/or aliphatic monocarboxylic acid, 10-25 wt.% of a polyol contg. 3-6 OH gps. per mol. and 10-20 wt.% of polycarboxylic acids or their anhydrides contg. 2-4 carboxyl gps. per mol. (A) has an acid number of no more than 30, pref. 20 mg KOH/g and a limiting viscosity value (measured in CCl4 at 20 deg.C of 4.5 to 6.0 ml/g. (B) comprises 15-40 wt.% of a conversion prod. obtd. either from 2 mol. of an OH-functional alkylether contg. at least 2 allylether gps. per mol. and 1 mol. of a tricarboxylic acid anhydride or from 1 mol. of an OH-functional alkyl ether contg. 3 or more alkylether gps. per mol. and 1 mol. of a dicarboxylic acid anhydride, and has an acid number corresp. to 1 free carboxylic acid gp. per mol. (A) and (B) are esterified at 170-230 deg.C to give an acid number of no more than 20 mg KOH/g and a limiting viscosity number (measured in chloroform at 20 deg.C) of 5.5 pref. 6.0-9.0 ml/g. The sum of the percentage values for the compsn. of the combinations of (A) and (B) and of (A1) to (A4) taken as solids amounts to 100.
机译:改性的醇酸树脂包含混合物。的comns。 (A)和(B),其中(A)包含60-80wt。%的干脂肪酸和/或碘值至少为110pref的油。 130-170,至多10重量%的芳族和/或脂族一元羧酸,10-25重量%的多元醇续。 3-6 OH gps。每摩尔和10-20重量%的多元羧酸或其酸酐续。 2-4个羧基gps。每摩尔(A)的酸值不超过30(优选)。 20 mg KOH / g和极限粘度值(在20°C下于CCl4中测量为4.5至6.0 ml / g(B))占15-40 wt。%的转化产物,从2 mol。每摩尔含至少2个烯丙基醚gps。和1摩尔三羧酸酐的OH-官能烷基醚,或每摩尔含3个或更多烷基醚gps和1摩尔的OH-官能烷基醚摩尔数的二羧酸酐,其酸值对应于每摩尔1游离羧酸gp。(A)和(B)在170-230℃酯化,酸值不超过20 mg KOH / g,极限粘度值(在20°C下于氯仿中测量)为5.5至6.0-9.0 ml / g。(A)和()的组合的百分比值之和B)和(A1)至(A4)的固体含量为100。

著录项

  • 公开/公告号AT396476B

    专利类型

  • 公开/公告日1993-09-27

    原文格式PDF

  • 申请/专利权人 VIANOVA KUNSTHARZ AKTIENGESELLSCHAFT;

    申请/专利号AT19910002331

  • 发明设计人

    申请日1991-11-25

  • 分类号C08G63/49;C09D167/08;

  • 国家 AT

  • 入库时间 2022-08-22 05:09:28

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