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Process of preparing catalyst supporting highly dispersed metal particles

机译:制备负载高分散金属颗粒的催化剂的方法

摘要

Disclosed is a process of preparing a catalyst supporting highly metal particles comprising, in the presence of carbon monoxide in a solution containing a metal-containing ion and a support on which metal particles produced by reduction of the metal-containing ion are supported, reducing by means of a reductant the metal-containing ion to the corresponding metal particles which are then supported on the support. According to the process of the present invention, because of the presence of the carbon monoxide which is supposed to have a function of depressing the deposition of a new metal particle present around the metal particles supported on the support, that is, the growth of the metal particles and another function of preventing the agglomeration among the metal particles supported, the catalyst of excellent properties having the metal particles supported and monodispersed on the support with the narrow particle size distiibution can be prepared of which an average particle size is not more than 20 ANGSTROM . After the preparation of the catalyst, the carbon monoxide can be easily taken out from the system so that no harmful effects are produced by the employment of the carbon monoxide. IMAGE
机译:公开了一种制备负载高金属颗粒的催化剂的方法,该催化剂包括在含有一含金属离子的溶液和一氧化碳的存在下,在包含一含金属离子的溶液中负载通过还原含金属离子而产生的金属颗粒的载体。还原剂是指将含金属的离子还原为相应的金属颗粒,然后将其负载在载体上。根据本发明的方法,由于一氧化碳的存在,该一氧化碳被认为具有抑制在支撑在载体上的金属颗粒周围存在的新金属颗粒的沉积的功能,即,可以制备平均粒径不大于20的具有优异性能的催化剂,该催化剂具有负载并单分散在载体上的金属颗粒,该金属颗粒负载并单分散在载体上,并且具有窄的粒径分布。昂斯特龙。制备催化剂后,可以很容易地将一氧化碳从体系中取出,因此使用一氧化碳不会产生有害影响。 <图像>

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