Process for preparing hydrophilic polyamide membrane filter media and product

摘要

A process is provided for preparing skinless hydrophilic alcohol-insoluble polyamide membranes by preparing a solution of an alcohol-insoluble polyamide resin in a polyamide solvent, inducing nucleation of the solution by controlled addition to the solution of a nonsolvent for the polyamide resin, under controlled conditions of concentration, temperature, addition rate, and degree of agitation to obtain a visible precipitate of polyamide resin particles which may or may not thereafter partially or completely redissolve, thereby forming a casting solution; spreading the casting solution on a substrate to form a thin film thereof on the substrate; contacting and diluting the film of casting solution with a mixture of solvent and nonsolvent liquids containing a substantial proportion of the solvent liquid, but less than the proportion in the casting solution, thereby precipitating polyamide resin from the casting solution in the form of a thin skinless hydrophilic membrane; and washing and drying the resulting membrane; the alcohol-insoluble polyamide membranes obtained by this process have the unusual property of being hydrophilic, i.e., readily wetted by water, have absolute particle removal capabilities of the order of 0.1 to 5 mu M or more, and are useful as filter media, particularly for producing bacterially sterile filtrates.