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And method responsive gel for selectively removing target material from the environment

机译:以及用于从环境中选择性去除目标物质的方法响应性凝胶

摘要

(57) responsive gel to selectively remove a target substance from [summary] environment is described. Polymer gels reversible response of the three-dimensional, consisting of the junction of at least two with respect to the target material capable of forming a binding site when they approach each other, to bind a target substance. The coupling portion is combined with a responsive polymer components correspond to changes in environmental conditions, is adapted to receive the expansion and volume shrinkage reversible. Polymer gel component has a volume contraction phase transition threshold that is different from the phase transition leap value of volume expansion. The responsive gels, when the polymer gel shrinks in the contracted state phase transition threshold, to allow the binding site to bind the target substance to each other and the coupling portion is to be placed so as to close enough to the target substance is built. When the polymer expands to expanded state in the phase transition threshold, the coupling portion is disconnected from each other. Method of removing a target substance from the environment is also described, to bind the target substance-binding site and has a binding affinity target substance, for the binding site of the polymer gel of the present invention, the coupling portion and to each other including the steps of contacting with the target substance, such that it is sufficiently close to the target, allows the gel is transferred to a contracted state. Method for selectively removing the target material selected from the target material solution, and other target materials are also described. Procedure for changing the environmental conditions, consists of varying the temperature of the gel in the preferred embodiment.
机译:(57)描述了从[环境]中选择性去除目标物质的响应性凝胶。聚合物凝胶的三维可逆响应(由至少两个相对于目标材料的连接点组成)在目标材料彼此接近时能够形成结合位点,以结合目标物质。偶联部分与响应性聚合物组分结合,以适应环境条件的变化,适于接收可逆的膨胀和体积收缩。聚合物凝胶组分的体积收缩相变阈值不同于体积膨胀的相变跃迁值。当聚合物凝胶在收缩状态相变阈值中收缩时,响应性凝胶允许结合位点将目标物质彼此结合,并且将放置偶联部分以与目标物质足够接近。当聚合物在相变阈值中膨胀至膨胀状态时,偶联部分彼此断开。还描述了从环境中去除目标物质的方法,其结合目标物质的结合位点并具有结合亲和力的目标物质,对于本发明的聚合物凝胶的结合位点,偶联部分彼此之间包括与目标物质接触的步骤,使其足够接近目标,可以使凝胶转移至收缩状态。还描述了用于从目标材料溶液中选择性地去除目标材料的方法以及其他目标材料。在优选的实施方案中,改变环境条件的程序包括改变凝胶的温度。

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