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METHOD OF HYDROGENATED CONJUGATED DIOLEFIN POLYMERS AND COPOLYMERS PREPARATION

机译:加氢共轭二烯烃聚合物的制备方法及共聚物的制备

摘要

A method of hydrogenated conjugated diolefin polymers preparation which is terminating a living polymer obtained by polymerising or copolymerising at least a conjugated diolefin with an organo-alkali metal polymerisation initiator in a suitable solvent, by the addition of hydrogen, and effecting selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer by contacting the polymer, in the absence of hydrocarbon lithium and alkoxy lithium compounds, with hydrogen in the presence of at least one bis(cyclopentadienyl)titanium compound.
机译:一种氢化共轭二烯烃聚合物的制备方法,该方法是通过在适当的溶剂中,通过添加氢,使至少一种共轭二烯烃与有机碱金属聚合引发剂聚合或共聚而终止的活性聚合物,该方法是通过添加氢,并使不饱和不饱和脂肪酸选择性氢化而实现的。在至少一种双(环戊二烯基)钛化合物存在下,在不存在烃基锂和烷氧基锂化合物的情况下,使聚合物与氢接触,使封端聚合物的共轭二烯烃单元中的双键与氢接触。

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