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Racemic body division of the hetero atomic substitution amine of 1 classes and 2 classes by the enzyme catalytic action acylation
Racemic body division of the hetero atomic substitution amine of 1 classes and 2 classes by the enzyme catalytic action acylation
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机译:1类和2类杂原子取代胺的外消旋体通过酶催化酰化作用的划分
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(57) Abstract In order to produce the hetero atomic substitution amine of 1 classes and 2 classes of optical activity from the racemic body which fits, a) under existing of hydrolase, enanchio the acylation to do racemic characteristic hetero atomic substitution amine, selectively the acid component 1 fluorine -, nitrogen -, next door -, oxygen - or making use of the ester which possesses the sulfur atom to the vicinity of the carbonyl carbon atom, b) separating the blend of the hetero atomic substitution amine of optical activity and the acylation of optical activity the hetero atomic substitution amine which is done, 1 enanchioma of hetero atomic substitution amine profitIn case of c) desire, the method of consisting of the fact that other enanchioma of this amine is acquired from the hetero atomic substitution amine which the acylation is done with amide division producing the hetero atomic substitution amine of 1 classes and 2 classes of optical activity.
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