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1 classes and the racemic split of the secondary amine with the enzyme catalytic action acylation

机译:1类和仲胺的外消旋拆分与酶催化作用的酰化作用

摘要

(57) Abstract Is done from the amine which, feature that already enanchioma of one side of amine is obtained with amide separation with c) desire, are suitable optical active 1 class and the secondary amine are produced from the racemic body where a) racemic amine and the Acid component fluorine -, nitrogen -, oxygen - or the ester which possesses the sulfur atom in the vicinity of the carbonyl carbon atom, the enantio the acylation do choice under existing of the hydrolase, b) separate the blend which consists of with optical active amine and optical active acylation amine, can obtain enanchioma of amine at the same time with that, the acylationManner is stated.
机译:(57)<摘要>由胺完成,该胺的特征是已经通过c)的酰胺分离而获得胺一侧的尿布瘤,是合适的旋光性一类,仲胺由外消旋体产生,其中)外消旋胺和酸成分的氟-氮-氧-或在羰基碳原子附近具有硫原子的酯,在水解酶存在下对映体进行酰化选择,b)分离混合物由光学活性胺和光学活性酰化胺组成,与此同时可获得胺的尿囊肿,说明了酰化方式。

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