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Fine polymer particles having heterogeneous phase structure, silver halide photographic light-sensitive material containing the fine polymer particles and image-forming method
Fine polymer particles having heterogeneous phase structure, silver halide photographic light-sensitive material containing the fine polymer particles and image-forming method
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机译:具有异相结构的聚合物细颗粒,包含该聚合物细颗粒的卤化银照相感光材料和成像方法
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摘要
Latex polymer of fine particles having a heterogeneous phase structure which comprises a core of a polymer having repeating units derived from a conjugated diene monomer and a shell of a polymer having repeating units derived from at least one ethylenically unsaturated monomer carrying an active methylene group; a silver halide photographic light-sensitive material comprises a core/shell latex polymer whose shell consists of a polymer having repeating units of an ethylenically unsaturated monomer represented by the formula: CH.sub.2 C(R.sup.1)- -L--X (wherein R. sup.1 represents H, alkyl or halogen, L represents a single bond or a bivalent coupling group, X represents an active methylene group, provided that L is bonded to X in the form of alkylene; and a method for forming images on a silver halide light-sensitive material which comprises exposing the material which comprises at least one light-sensitive silver halide emulsion layer and at least one hydrophilic colloidal layer either of which comprises a latex polymer having active methylene groups and developing the exposed material with a developer which comprises a dihydroxybenzene developing agent and an auxiliary developing agent showing superadditivity, the pH increase observed when adding 0.1 mole/l developer of NaOH to the developer . ltoreq.0.25; 9.5 initial pH of the developer 11.0; the amount of the developer supplemented . ltoreq.225 ml/m.sup.2.
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