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Fine polymer particles having heterogeneous phase structure, silver halide photographic light-sensitive material containing the fine polymer particles and image-forming method

机译:具有异相结构的聚合物细颗粒,包含该聚合物细颗粒的卤化银照相感光材料和成像方法

摘要

Latex polymer of fine particles having a heterogeneous phase structure which comprises a core of a polymer having repeating units derived from a conjugated diene monomer and a shell of a polymer having repeating units derived from at least one ethylenically unsaturated monomer carrying an active methylene group; a silver halide photographic light-sensitive material comprises a core/shell latex polymer whose shell consists of a polymer having repeating units of an ethylenically unsaturated monomer represented by the formula: CH.sub.2 C(R.sup.1)- -L--X (wherein R. sup.1 represents H, alkyl or halogen, L represents a single bond or a bivalent coupling group, X represents an active methylene group, provided that L is bonded to X in the form of alkylene; and a method for forming images on a silver halide light-sensitive material which comprises exposing the material which comprises at least one light-sensitive silver halide emulsion layer and at least one hydrophilic colloidal layer either of which comprises a latex polymer having active methylene groups and developing the exposed material with a developer which comprises a dihydroxybenzene developing agent and an auxiliary developing agent showing superadditivity, the pH increase observed when adding 0.1 mole/l developer of NaOH to the developer . ltoreq.0.25; 9.5 initial pH of the developer 11.0; the amount of the developer supplemented . ltoreq.225 ml/m.sup.2.
机译:具有异相结构的细粒胶乳聚合物,其包含具有衍生自共轭二烯单体的重复单元的聚合物的核和具有衍生自至少一种带有活性亚甲基的烯键式不饱和单体的重复单元的聚合物的壳;卤化银照相感光材料包括核/壳胶乳聚合物,其壳由具有以下化学式表示的烯键式不饱和单体的重复单元的聚合物组成:CH 2 C(Rups.1)-L -X(其中R.sup.1代表H,烷基或卤素,L代表单键或二价偶联基团,X代表活性亚甲基,条件是L以亚烷基的形式与X结合;和在卤化银感光材料上形成图像的方法,该方法包括曝光包含至少一层感光卤化银乳剂层和至少一层亲水胶体层的材料,其中所述亲水胶体层均包含具有活性亚甲基的胶乳聚合物,并显影该材料。含有二羟基苯显影剂和显示出超加和性的辅助显影剂的显影剂的曝光材料,当向显影剂中添加0.1摩尔/升的NaOH显影剂时,pH升高。 ltoreq.0.25; 9.5显影剂的初始pH为11.0;补充的显影剂数量。 ≤225ml / m.sup.2。

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