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HYDROTALCITE-LIKE COMPOUND AND ITS MANUFACTURING METHOD

机译:类水滑石化合物及其制备方法

摘要

PROBLEM TO BE SOLVED: To provide a hydrotalcite-like compound (a lamellar double hydroxide) containing metal ingredients originating from melting dust and its manufacturing method. SOLUTION: Acid-soluble metal ingredients (including iron and zinc) are extracted by treating melting dust discharged from a melting furnace for cast iron with hydrochloric acid. Hydrogen peroxide solution is added to the extracted liquid to oxidize residual bivalent iron to make it trivalent iron. A magnesium-containing salt (such as magnesium chloride) is blended in the liquid and the pH of the liquid is controlled so as to precipitate a product. The precipitated product is separated and is treated by alkaline water heat treatment if necessary. The obtained product shows XRD pattern characteristic of the hydrotalcite-like compound and has good ion-exchange performance, especially with nitrate ion.
机译:解决的问题:提供一种类似水滑石的化合物(层状双氢氧化物),其包含源自熔融粉尘的金属成分及其制造方法。解决方案:酸溶性金属成分(包括铁和锌)是通过用盐酸处理从铸铁熔炉中排出的熔尘来提取的。将过氧化氢溶液添加至提取液中,以氧化残留的二价铁,使其成为三价铁。将含镁的盐(例如氯化镁)掺入液体中,并控制液体的pH以沉淀产物。分离出沉淀的产物,并在必要时通过碱水热处理进行处理。所得产物显示出水滑石样化合物的XRD图谱特征,并且具有良好的离子交换性能,尤其是与硝酸根离子的离子交换性能。

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