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Polyurethane prepolymers with reduced functionality having terminal alkoxysilane and OH groups, a method of preparing them and their use

机译:具有末端烷氧基硅烷基和OH基团的官能度降低的聚氨酯预聚物,其制备方法及其用途

摘要

The present invention relates to polyurethane prepolymer having terminal alkoxysilane and OH groups which is the reaction product of ;A) a polyurethane prepolymer prepared by incomplete reaction of ;i) an aromatic, aliphatic or cycloaliphatic diisocyanate component having an NCO content of 20 to 60% by weight with ;ii) a polyol component comprising a polyoxyalkylene diol having a number average molecular weight of 3000 to 20,000, ;wherein the reaction is stopped after 50 to 90% of the OH groups of component ii) are reacted and 10 to 50% are unreacted, with ;B) a compound having alkoxysilane and amino groups, preferably a compound containing alkoxysilane and aspartate groups. ;The present invention also relates to a process for preparing these polyurethane prepolymers containing terminal alkoxysilane and OH groups and to isocyanate-free, sealants, adhesives, primers and coatings containing these polyurethane prepolymers containing terminal alkoxysilane and OH groups as binders.
机译:本发明涉及具有末端烷氧基硅烷基和OH基团的聚氨酯预聚物,其是; A)通过不完全反应制备的聚氨酯预聚物; i)NCO含量为20-60%的芳族,脂族或脂环族二异氰酸酯组分。 ii)包含数均分子量为3000至20,000的聚氧化烯二醇的多元醇组分;其中ii)的50至90%的OH基团与10至50%的羟基发生反应后,反应停止-B)是具有烷氧基硅烷基和氨基的化合物,优选含有烷氧基硅烷基和天冬氨酸基的化合物。本发明还涉及制备这些含有末端烷氧基硅烷基和OH基团的聚氨酯预聚物的方法,并且涉及不含异氰酸酯的密封剂,粘合剂,底漆和涂料,其中含有这些含有末端烷氧基硅烷基和OH基团的聚氨酯预聚物作为粘合剂。

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