Ftalamida Derivatives, production of intermediate compounds of the same, and Methods for using insecticides agrohorticolas

摘要

A phthalamide derivative characterized in that it is represented by the following general formula (I): EMI FILE = "00049445_1" ID = "1" IMF = JPEG where R1, R2 and R3, which may be the same or different, represent atom of hydrogen, C3-C6 cycloalkyl group, C3-C6 halocycloalkyl group or -A1- (G) r (in this formula, A1 represents C1-C8 alkylene group, C3-C6 alkenylene group or C3-C6 alkynylene group; G which can be the same or different, it represents hydrogen atom, halogen atom, cyano group, nitro group, C1-C6 haloalkyl group, C3-C6 cycloalkyl group, C3-C6 halocycloalkyl group, C1-C6 alkoxycarbonyl group,di (C1-C6) alkoxyphosphoryl group where (C1-C6) groups can be the same or different, di (C1-C6) alkoxythiophosphoryl group where (C1-C6) groups can be the same or different, diphenylphosphine group, diphenylphosphono group , phenyl group, substituted phenyl groups having at least one, the same, or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1 haloalkoxy group -C6, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group and C1-C6 haloalkylsulfonyl group,grupo heteroc clico (como se utiliza en la presente el t rmino grupo heteroc clico significa grupo piridilo grupo pirimidinilo grupo piridin-N- xido grupo furilo grupo tienilo grupo tetrahidrofurilo grupo tetrahidrotienilo grupo tetrahidropiranilo grupo oxazolilo grupo isoxazolilo grupo tiazolilo grupo oxadiazolilo grupo isotiazolilo grupo imidazolilo grupo substituted heterocyclic group (the term heterocyclic group is the same as defined above) which has at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1- alkoxy group C6, C1-C6 haloalkoxy group, C1-C6 alkylthio group, - 2-C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, or -Z3- R4 (in this formula, Z3 represents -O-,- yes.-So...-S02...-N (R5) - (en esta f rmula R5 representa tomo de hidr geno grupo alquilcarbonilo C1-C6 grupo haloalquilcarbonilo C1-C6 grupo alcoxicarbonilo C1-C6 grupo fenilcarbonilo grupo fenilcarbonilo sustituido que posee por lo menos uno iguales o diferentes sustituyentes seleccionados del grupo on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group, group C1-C6 alkylthio, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, and C1-C6 haloalkylsulfonyl group, C1-C6 alkylsulfonyl group, or C1-C6 haloalkylsulfonyl group),-C (= O) - or -C (= NOR6) - (in this formula, R6 represents hydrogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C3-C6 alkenyl group, C3-C6 haloalkenyl group, C3-C6 alkynyl group, C3-C6 cycloalkyl group, C1-C4 phenylalkyl group, or substituted C1-C4 phenylalkyl group having at least one, the same or different substituents selected from the group consisting of atom of halogen, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group,1. C1-C6 halogenated tar group,and R4 represents hydrogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C3-C6 alkenyl group, C3-C6 haloalkenyl group, C3-C6 alkynyl group, C3-C6 cycloalkyl group, group C3-C6 halocycloalkyl, C1-C6 alkoxy group C1-C6 alkyl, C1-C6 alkylthio group C1-C6 alkyl, formyl group, C1-C6 alkylcarbonyl group, C1-C6 haloalkylcarbonyl group, C1-C6 alkoxycarbonyl group, (C1) mono group -C6) alkylaminocarbonyl, di (C1-C6) alkylaminocarbonyl group where the (C1-C6) groups can be the same or different, mono (C1-C6) alkylaminothiocarbonyl group,di (C1-C6) alkylaminothiocarbonyl group where (C1-C6) groups can be the same or different, di (C1-C6) alkoxyphosphoryl group where (C1-C6) groups can be the same or different, di (C1 -C6) alkoxythiophosphoryl wherein (C1-C6) groups may be the same or different, phenyl group, substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1- alkyl group C6, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group, C2-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group,C1-C6 alkylsulfonyl group and C1-C6 haloalkylsulfonyl group, phenylalkyl-C4 alkyl group, substituted (C1-C4) phenyl group having, on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1 haloalkylsulfinyl group -C6, C1-C6 alkylsulfonyl group and C1-C6 haloalkylsulfonyl group, heterocyclic group (the term heterocyclic group is the same as defined above),or substituted heterocyclic group (the term heterocyclic group is the same as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, alkoxy group C1-C6, C1-C6 haloalkoxy group, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group and C1-C6 haloalkylsulfonyl group);R is an integer from 1 to 4;furthermore, R1 and R2 can be linked together to form 4- to 7-membered rings that can be intercepted by 1 to 3, the same or different oxygen atom, sulfur atom or nitrogen atom; X, which may be the same or different, represents halogen atom, cyano group, nitro group, amino group, C1-C6 alkyl group, C1-C6 haloalkyl group, C3-C6 cycloalkyl group, C3-C6 halocycloalkyl group, C1- alkoxy group. C6, C1-C6 haloalkoxy group, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, C1-C6 haloalkylsulfonyl group ) alkylamino,di (C1-C6) alkylamino group wherein (C1-C6) groups may be the same or different, C1-C6 alkylcarbonylamino group, C1-C6 haloalkylcarbonylamino group, C1-C6 alkoxycarbonyl group, or tri (C1-C6) alkylsilylethynyl group where the groups (C1-C6) can be the same or different; n represents an integer of value 0 to 4; in addition, X can bond together with the atom carbon in the adjacent phenyl ring to form a fused ring (as used herein, the term "fused ring" means -3-naphthalene, tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman, isochroman, indole, indoline, benzodioxane, benzodioxol, benzofuran, dihydrobenzofuran,benzotiofeno dihidrobenzotiofeno benzoxazol benzotiazol benzimidazol o indazol)and said fused ring may have at least one of the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group, alkylthio group C1-C6, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, C1-C6 haloalkylsulfonyl group, substituted phenyl group having at least one, the same, or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group, C1-C6 haloalkoxy group,C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, and C1-C6 haloalkylsulfonyl group, heterocyclic group (the term heterocyclic group is the same as defined above),and substituted heterocyclic group (the term heterocyclic group is the same as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, alkoxy group C1-C6, C1-C6 haloalkoxy group, C1-C6 alkylthio group, C1-C6 haloalkylthio group, C1-C6 alkylsulfinyl group, C1-C6 haloalkylsulfinyl group, C1-C6 alkylsulfonyl group, and C1-C6 haloalkylsulfonyl group; Q represents an optionally substituted heterocyclic group, or fused heterocyclic group, N- content,S- and O- selected from the group consisting of the following formulas Q1, Q2, Q4, to Q6, Q8 to Q10, Q12, Q16, Q17, Q19 and Q26 to Q34 EMI FILE = "00049445_2" ID = "2" MFI = JPEG (in these formulas, and which can be the same or different, it represents halogen atom, cyano group, nitro group, C3-C6 halocycloalkyl group, phenyl group, substituted phenyl group that has at least one, the same or different substituents selected from the group consisting of d atom