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POLYMER LATEX COMPOSITION, DIP-FORMED ARTICLE AND PROCESS FOR PRODUCING DIP-FORMED ARTICLE

机译:聚合物乳胶组合物,浸涂成型制品以及制备浸涂成型制品的方法

摘要

A polymer latex composition comprising a polymer with a glass transition temperature (Tg) of -85 to +30°C and a polymer with Tg of +40 to +140°C, wherein the polymers are dispersion-stabilized with polyvinyl alcohol (PVA). Preferably, the polymer latex composition is (1) a coating composition comprising a first polymer with Tg of -20 to +30°C and a second polymer with Tg of +60 to +140°C, or (2) used for preparation of a dip-forming coagulating composition comprising a coagulant and a polymer latex comprising copolymer particles each having PVA bonded thereto, which are obtainable by polymerizing a monomer capable of forming a third polymer with Tg of -85 to +10°C in a first step, and then a monomer capable of forming a fourth polymer with Tg of +40 to +140°C in the sequential step. The polymerization for preparing the first through fourth polymers is carried out in the presence of PVA in an aqueous medium.
机译:聚合物胶乳组合物,其包含玻璃化转变温度(Tg)为-85至+ 30°C的聚合物和Tg为+40至+ 140°C的聚合物,其中所述聚合物用聚乙烯醇(PVA)分散稳定化。优选地,聚合物胶乳组合物是(1)包含Tg为-20至+ 30℃的第一聚合物和Tg为+60至+ 140℃的第二聚合物的涂料组合物,或(2)用于制备包含凝结剂和聚合物胶乳的浸液形成凝结组合物,所述凝乳剂和聚合物胶乳包含各自键合有PVA的共聚物颗粒,可通过在第一步中聚合能够形成第三聚合物的Tg为-85至+ 10°C的单体获得,然后在顺序步骤中能够形成Tg为+40至+ 140℃的第四聚合物的单体。用于制备第一至第四聚合物的聚合是在水介质中在PVA存在下进行的。

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