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RADIATION-SENSITIVE RESIN COMPOSITION, PROCESS FOR PRODUCING THE SAME AND PROCESS FOR PRODUCING SEMICONDUCTOR DEVICE THEREWITH

机译:辐射敏感树脂组合物,其制造过程及其制造半导体器件的过程

摘要

A chemical amplification type radiation-sensitive resin composition comprising at least a base resin [1] composed of an alkali soluble resin or an alkali insoluble or alkali hardly soluble resin protected by an acid dissociable protective group wherein the content of ultrahigh molecular weight components whose weight average molecular weight in terms of polystyrene as measured by gel permeation chromatography according to multiangular light scattering is 1000 thousand or greater is 1 ppm or less, a photoacid generator [2] capable of generating an acid upon exposure to radiation and a solvent [3]. This radiation-sensitive resin composition is applied onto work object (2) by coating so as to form photoresist layer (3), and subjected to exposure and development so as to form 0.2 μm or less fine resist pattern (4). Thereafter, dry etching is performed so as to effect pattering for semiconductor device gate electrode, hole configuration, channel configuration, etc. In this manner, patterning with minimized occurrence of pattern defects such as microbridge can be realized.
机译:化学放大型放射线敏感性树脂组合物,其至少包含由酸分解性保护基保护的碱可溶性树脂或碱不溶性或碱难溶性树脂构成的基础树脂[1],其中,超高分子量成分的含量为通过凝胶渗透色谱法根据多角度光散射测得的以聚苯乙烯计的平均分子量为1000千或更大为1ppm或更小,能够在暴露于辐射时产生酸的光产酸剂[2]和溶剂[3]。 。通过涂布将该放射线敏感性树脂组合物涂覆到工件(2)上以形成光致抗蚀剂层(3),并对其进行曝光和显影以形成0.2μm或更小的精细抗蚀剂图案(4)。此后,执行干法蚀刻以实现对半导体器件栅电极,孔构型,沟道构型等的图案化。以这种方式,可以实现图案缺陷(例如微桥)的发生最少的图案化。

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