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As a sensitizer the useful ruthenium complex, the oxide semiconductor electrode and solar battery null formula (i)

机译:作为敏化剂,有用的钌配合物,氧化物半导体电极和太阳能电池无效的化学式(i)

摘要

PROBLEM TO BE SOLVED: To provide a material capable of utilizing light energy with higher efficiency.;SOLUTION: This ruthenium complex is represented by formula (I): RuLL'X [wherein, L is a 2,2'-6'-2"-terpyridine derivative containing any of carboxy group, sulfonate group and phosphate group which are at least one binding group; each binding group is a salt of an acid with an alkali metal, ammonium or the like; and L' is a diketonate represented by the formula (wherein, R1, R2 and R3 are each independently an alkyl, an alkoxyalkyl, an aminoalkyl, a perfluoroalkyl, an aryl or hydrogen atom; and X is a monodentate ligand selected from a halide, cyano group, thiocyano group and thiolate)].;COPYRIGHT: (C)2003,JPO
机译:解决的问题:提供一种能够高效利用光能的材料;解决方案:该钌配合物由式(I)表示:RuLL'X [其中,L为2,2'-6'-2 “-叔吡啶衍生物,其含有至少一个结合基团的羧基,磺酸根基团和磷酸根基团中的任何一个;每个结合基团是酸与碱金属,铵等的盐;并且L'是由以下基团表示的二酮酸酯式(其中,R 1 ,R 2 和R 3 分别独立地为烷基,烷氧基烷基,氨基烷基,全氟烷基,芳基或氢原子; X是选自卤化物,氰基,硫氰基和硫醇盐的单齿配体)];版权:(C)2003,JPO

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