ABSTRACT METHODS FOR THE OPTIMIZATI OFSUBSTRATE ETCHING IN A PLASMA PRO SSING SYSTEMA method of etching a substrate in a plasma processing system is sclosed. The substrate has a semi-conductor layer, a first barrier layer disposed above the semi-conductor layer, a low-k layer sposed above the first barrier layer, a third hard mask layer disposed above the low-k layer; a second hard mask layer disposed a ve the third hard mask layer, and a first hard mask layer disposed above the second hard mask laver. The method includes altem vely etching the substrate with a first etchant and a second etchant, wherein the first etchant has a low selectivity to a first hard ask material of the first hard mask layer, a third hard mask material of the a third hard mask layer, and a first barrier layer in 'al of the first barrier layer, but a high selectivity to a second hard mask material of the second hard mask layer; and wherein t second etchant has a high selectivity to the first hard mask material of the first hard mask layer, the third hard mask material oft third hard mask layer, and the first barrier layer material of the first harder layer, and the first etchant has a low selectivity to th second hard mask material of the second hard mask layer.17ABSTRACT METHODS FOR THE OPTIMIZATION OF SUBSTRATE ETCHING IN APLASMA PROCESSING SYSTEMA method of etching a substrate in a plasma processing system is disclosed. The substrate has a semi-conductor layer, a first barrier layer disposed above the semi-conductor layer, a low-k layer disposed above the first barrier layer, a third hard mask layer disposed above the low-k layer; a second hard mask layer disposed above the third hard mask layer, and a first hard mask layer disposed above the second hard mask layer. The method includes alternatively etching the substrate with a first etchant and a second etchant, wherein the first etchant has a low selectivity to a first hard mask material of the first hard mask layer, a third hard mask material of the a third hard mask layer, and a first barrier layer material of the first barrier layer, but a high selectivity to a second hard mask material of the second hard mask layer; and wherein the second etchant has a high selectivity to the first hard mask material of the first hard mask layer, the third hard mask material of the third hard mask layer, and the first barrier layer material of the first barrier layer, and the second etchant has a low selectivity to the second hard mask material of the second hard mask layer.
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