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Composition based on cerium oxide and zirconium oxide and having high specific surface area and high oxygen storage capacity, and method for producing the same

机译:基于氧化铈和氧化锆并且具有高比表面积和高储氧能力的组合物及其制备方法

摘要

A composition based on cerium oxide and on zirconium oxide and, optionally, on a yttrium, scandium or rare-earth metal oxide. The cerium/zirconium atomic proportion is at least 1. The compound exhibits a specific surface, after calcination for 6 hours at 900° C. of at least 35 m2/g and an oxygen storage capacity at 400° C. of at least 1.5 ml of O2/g. The composition is prepared by mixing, in a liquid medium, a cerium compound, a zirconium compound and, if appropriate, a yttrium, scandium or rare-earth metal compound; heating and calcining the precipitate obtained; and using a zirconium solution having an amount of base necessary to reach the equivalent point during an acid/base titration of the solution having a molar ratio of OH-/Zr=1.65. The composition thus obtained is used in the manufacture of multi-functional catalysts.
机译:一种基于氧化铈和氧化锆以及任选地基于钇,scan或稀土金属氧化物的组合物。铈/锆原子比例为至少1。该化合物在900℃下煅烧6小时后至少为35m2 / g,并且在400℃下储氧容量为至少1.5ml后显示出比表面。 O2 / g。通过在液体介质中混合铈化合物,锆化合物和合适的话钇、,或稀土金属化合物来制备该组合物;加热并煅烧得到的沉淀物;并且使用锆溶液,其具有在摩尔比为OH- /Zr≤1.65的溶液的酸/碱滴定期间达到等效点所需的碱量。如此获得的组合物用于制造多功能催化剂。

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