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Process for Reducing Fouling From Flash/Separation Apparatus During Cracking of Hydrocarbon Feedstocks

机译:减少烃类原料裂解过程中闪蒸/分离装置结垢的方法

摘要

Hydrocarbon feedstock containing resid is cracked by a process comprising: (a) heating the hydrocarbon feedstock; (b) mixing the heated hydrocarbon feedstock with steam and optionally water to form a mixture stream; (c) introducing the mixture stream to a flash/separation apparatus to form i) a vapor phase at its dew point which partially cracks and loses/or heat causing a temperature decrease and partial condensation of the vapor phase in the absence of added heat to provide coke precursors existing as uncoalesced condensate, and ii) a liquid phase; (d) removing the vapor phase as overhead and the liquid phase as bottoms from the flash/separation apparatus; (e) treating the overhead by contacting with a hydrocarbon-containing nucleating liquid substantially free of resid and comprising components boiling at a temperature of at least about 260° C. (500° F.) under conditions sufficient to at least partially coalesce the coke precursors to provide coke precursor liquid, in the form of hydrocarbon droplets or a continuous hydrocarbon liquid phase; (f) collecting and removing the droplets; (g) directing the treated overhead from which the droplets are removed, to a heater to provide a heated vapor phase; (h) cracking the heated vapor phase in a radiant section of a pyrolysis furnace to produce an effluent comprising olefins, the pyrolysis furnace comprising a radiant section and a convection section; and (i) quenching the effluent and recovering cracked product therefrom. An apparatus for carrying out the process is also provided.
机译:包含残油的烃原料通过以下方法裂化:(a)加热烃原料; (b)将加热的烃原料与蒸汽和任选的水混合以形成混合物流; (c)将混合物料流引入闪蒸/分离设备以形成i)在其露点的气相,该气相在不添加热量的情况下部分裂化和损失//热量导致温度降低和气相的部分冷凝。提供以未凝结的冷凝液形式存在的焦炭前体,和ii)液相; (d)从闪蒸/分离设备中除去作为塔顶馏出物的蒸气相和作为塔底馏出物的液相; (e)通过与含烃成核液体接触处理塔顶馏出物,所述成核液体基本上不含残渣并且包含在至少约260℃(500°F)的温度下沸腾的组分,所述组分至少足以使焦炭部分聚结以烃小滴或连续烃液相形式提供焦炭前体液体的前体; (f)收集和清除飞沫; (g)将去除了液滴的处理过的塔顶引到加热器以提供加热的蒸气相; (h)在热解炉的辐射段中裂化加热的蒸气相以产生包含烯烃的流出物,该热解炉包括辐射段和对流段; (i)淬灭流出物并从中回收裂解产物。还提供了用于执行该过程的设备。

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