Three different types of VGO were selected and cut into various distillates by true boiling-point distillation (TBD), and the distillates were further separated into different components (saturates, aromatics and resins) via solid phase extraction (SPE). The hydrocarbon components in saturates and aromatics were characterized on the quasi-molecular level by GC/MS and GC/TOF MS. Cracking reactions of VGO, their distillates, and hydrocarbon components (saturates and aromatics) were performed on an ACE (model AP) unit. Nine correlation parameters (mainly based on the previous assumption of basic structure units, BSU) which could better reflect the structures and compositions of hydrocarbons were put forward based on the quasi-molecular level analysis data, and correlated with FCC product distribution by multi-regression method. A series of correlation formulas were obtained. The formulas were further verified by comparing experimental and calculated FCC yields emanated from two other VGO feedstocks.
展开▼
