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METHOD FOR PREPARATION OF TRANSPARENT MOULDING BASED ON BLEND OF THERMOPLASTIC POLYMER AND THERMOSETTING POLYMER

机译:基于热塑性聚合物和热固性聚合物共混物的透明模具的制备方法

摘要

PROBLEM TO BE SOLVED: To provide a method of cast moulding in which a transparent article with non- or very little scattering can be obtained.;SOLUTION: The method of preparing a transparent moulding comprising a blend of a first thermoset polymeric material forming the matrix of the transparent moulding and a second polymeric material dispersed within the first material comprises at least the following stages: (i) preparation of a liquid polymerizable mixture by dissolving the second polymeric material in a thermosetting polymerizable composition that is a precursor of the first thermoset polymeric material, (ii) filling of a mould with the liquid polymerizable mixture obtained in stage (i), (iii) cooling of the liquid polymerizable mixture in the mould to the temperature T less than or equal to 0°C, (iv) initiation of the polymerization of the cooled liquid polymerizable mixture at the temperature T' less than or equal to 0°C, (v) continuation of the polymerization of the liquid polymerizable mixture until a hardened blend of polymers is obtained, and (vi) removal of the moulding formed from the blend of polymers from the mould. The invention also relates to a transparent moulding obtainable by such a method comprising a blend of polymers, at least one of which is a thermosetting polymer.;COPYRIGHT: (C)2009,JPO&INPIT
机译:解决的问题:提供一种浇铸成型的方法,其中可获得无或几乎没有散射的透明制品。解决方案:制备透明成型的方法,该方法包括形成基质的第一热固性聚合物材料的共混物透明模制件和分散在第一材料中的第二聚合物材料的步骤至少包括以下步骤:(i)通过将第二聚合物材料溶解在作为第一热固性聚合物前体的热固性可聚合组合物中来制备液体可聚合混合物。材料,(ii)用在步骤(i)中获得的液体可聚合混合物填充模具,(iii)将模具中的液体可聚合混合物冷却至小于或等于0摄氏度的温度T,(iv)引发在小于或等于0℃的温度T'下冷却的液态可聚合混合物的聚合反应,(v)液体的聚合继续该可聚合混合物直至获得聚合物的硬化共混物,和(vi)从模具中除去由聚合物共混物形成的模制品。本发明还涉及通过这样的方法可获得的透明模制品,该方法包括聚合物的共混物,其中至少一种是热固性聚合物。;版权所有:(C)2009,JPO&INPIT

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