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Room temperature vulcanizing one-component silicone rubber formulations containing a hydrophobic silica

机译:含有疏水性二氧化硅的室温硫化单组分硅橡胶配方

摘要

PROBLEM TO BE SOLVED: To provide a one-component type silicone rubber preparation vulcanizable at a room temperature containing hydrophobic silica.;SOLUTION: The silicone rubber composition comprises 0.5-60 mass% hydrophobic silica having a carbon content of 3.1%, a methanol wetness of 60%, a reflectance of 94%, a BET/CTAB ratio of 1 and 3, a DBP absorption of 230 g/100 g, a BET surface area of 50-110 m2/g, a CTAB surface area of 30 m2/g, a water vapor absorption at 30°C under 30RH of 1.3 and a water vapor absorption at 30°C under 70RH of 1.7, and 40-99.5 mass% of an organopolysiloxane of the formula: ZnSiR3-n-O-[SiR2O]x-SiR3-n-Z'n (wherein the variations are as defined in Claims), and therefore, the following effect is obtained: in vulcanizing a silicon rubber, a high reinforcing effect as well an extraordinary low water absorption, a high whiteness and a high accurate control can be attained, and further, a storage stable rheological property can also be attained.;COPYRIGHT: (C)2003,JPO
机译:解决的问题:提供一种在室温下可硫化的含有疏水性二氧化硅的单组分型硅橡胶制剂。解决方案:硅橡胶组合物包含0.5-60质量%的碳含量> 3.1%的疏水性二氧化硅,甲醇湿度> 60%,反射率> 94%,BET / CTAB比> 1和<3,DBP吸收量<230 g / 100 g,BET表面积50-110 m 2 < / Sup> / g,CTAB表面积> 30 m 2 / g,30RH在30RH下的水蒸气吸收率<1.3,70RH在70RH下在30℃的水蒸气吸收率分子式为Z n SiR 3-n -O- [SiR 2 O的有机聚硅氧烷的<1.7和40-99.5质量% ] x -SiR 3-n -Z' n (其中的变化与权利要求中的定义相同),因此具有以下效果获得:在硫化硅橡胶时,高补强效果以及极低的吸水率,高白度和高精度控制可以;此外,还可以获得稳定的流变性能。;版权所有:(C)2003,日本特许厅

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