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BROMINE-SUBSTITUTED RYLENE TETRACARBOXYLIC ACID DERIVATIVES, AND THE USE THEREOF

机译:溴取代的亚甲基四羧酸衍生物及其用途

摘要

The present invention relates to bromine-substituted rylene tetracarboxylic acid derivatives of the general formula (I), wherein n is 2, 3, or 4; Rn1, Rn2, Rn3, and Rn4 are halogen or cyano, specifically for Br, wherein at least one of the radicals Rn1, Rn2, Rn3 or Rn4 is Br; Y1 and Y2 are O or NRb; wherein Rb is hydrogen or an organyl radical; Z1, Z2, Z3 and Z4 are O, wherein in case that Y1 is NRa, one of the radicals Z1 and Z2 may also be NRC, wherein the radicals Ra and Rc together are a bridging group having 2 to 5 atoms between the flanking bonds, and wherein in case Y2 is NRb, one of the radicals Z3 and Z4 may also be NRd, wherein the radicals Rb und Rd together are a bridging group having 2 to 5 atoms between the flanking bonds; to the production of compounds of the general formula I by means of reaction of a corresponding compound, wherein at least one of the radicals Rn1, Rn2, Rn3 and/or Rn4 is hydrogen, having N,N'-dibromisocyanuric acid, and to the use of compounds of the general formula I as emitter materials, charge transport materials, or exciton transport materials.
机译:本发明涉及通式(I)的溴取代的亚芳基四羧酸衍生物,其中n为2、3或4; n为2或3。 Rn1,Rn2,Rn3和Rn4是卤素或氰基,特别是对于Br,其中基团Rn1,Rn2,Rn3或Rn4中的至少一个是Br; Y1和Y2为O或NRb;其中Rb是氢或有机基团; Z 1,Z 2,Z 3和Z 4为O,其中在Y 1为NRa的情况下,基团Z 1和Z 2之一也可以为NRC,其中Ra和R c一起为在侧键之间具有2至5个原子的桥连基团并且,在Y2为NRb的情况下,基团Z3和Z4也可以为NRd,其中基团Rb和Rd一起为在侧键之间具有2至5个原子的桥连基团。通过相应的化合物的反应制备通式I的化合物,其中基团Rn1,Rn2,Rn3和/或Rn4中的至少一个是氢,具有N,N'-二溴异氰尿酸,并且通式I的化合物用作发射体材料,电荷传输材料或激子传输材料的用途。

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