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SILICONE COMPOSITE THAT CAN BE RETICULATED FOR PRODUCING ANTI-ADHESIVE COATINGS FOR FLEXIBLE SUPPORTS AND ADDITIVE TO PROMOTE ADHESION CONTAINED IN THIS COMPOSITE
SILICONE COMPOSITE THAT CAN BE RETICULATED FOR PRODUCING ANTI-ADHESIVE COATINGS FOR FLEXIBLE SUPPORTS AND ADDITIVE TO PROMOTE ADHESION CONTAINED IN THIS COMPOSITE
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机译:硅酮复合材料,可网状生产用于柔性支撑的防粘涂层,并有助于促进该复合材料中的附着力
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摘要
The area addressed by the invention is that of silicone composites that are subject to reticulation or have been reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds are of the type that contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. The objective is to propose new liquid silicone compounds that can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed); these latter properties are in particular the result of an additive to help it stick. In order to achieve this aim, the invention proposes silicone compounds in which the attachment-enhancing additive is: M [D]d° [Dalcoxy ]da [Depoxy ]de [D']d' [M']m' M; where 0 = d° 500; 0=da= 50; 1 = de=40; 0 = d' 1; 0 = d' 0.1; 0 = m' 1; d'+m' is less than 1, preferably less than or equal to 0.5. Uses: anti-adhesive silicone coatings obtained by reticulation/polyaddition for films on paper and on polymers (PET).
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机译:本发明涉及的领域是可网状化或已经网状化的有机硅复合材料的领域,特别是用于为天然或合成形式的挠性基材(例如纸或类似物)形成涂料或防水和防粘膜聚合物薄膜。这些化合物是包含具有SiH单元的网状聚有机硅氧烷和优选为乙烯基化的不饱和聚有机硅氧烷的类型,该不饱和聚有机硅氧烷适合于在加成反应中和在铂的存在下与网状剂反应以在挠性基材上形成网状抗粘涂层。 ,再加上至少一种添加剂(D)以促进对其的粘附。目的是提出无需使用溶剂就可以应用的新型液态有机硅化合物,这是有益的,可以立即网状形成可挠性基材的防粘和/或防水涂层,从而提供非常高质量的网状有机硅涂料,特别是在粘附/粘附于基材方面,更难擦掉,并且具有抗粘连特性(在高速下充分增加了剥离力);后者的这些特性尤其是助粘剂的结果。为了实现该目的,本发明提出了硅氧烷化合物,其中增强附着的添加剂为:M [D] d°[Dalcoxy] da [Depoxy] de [D'] d'[M'] m'M;其中0 <= d°<500; 0 <= da <= 50; 1 <= de <= 40; 0 <= d'<1; 0 <= d'0.1; 0 <= m'<1; d'+ m'小于1,优选小于或等于0.5。用途:通过在纸上和在聚合物(PET)上成网状/加聚而成的有机硅防粘涂料。
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