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PROCESS FOR PRODUCTION OF CROSS COPOLYMERS, CROSS COPOLYMERS OBTAINED BY THE PROCESS, AND USE THEREOF

机译:交叉共聚物的生产方法,该方法获得的交叉共聚物及其用途

摘要

To provide a novel cross copolymer and resin composition which are improved in heat resistance and compatibility over conventional ethylene/aromatic vinyl compound copolymers and which have low crystallinity, are excellent in softness, transparency and compatibility and show mechanical properties similar to soft vinyl chloride resins, as compared with conventional cross copolymers.;A process for producing a cross copolymer, which comprises a coordination polymerization step and a subsequent anionic polymerization step, wherein in the coordination polymerization step, copolymerization of an olefin monomer, an aromatic vinyl compound monomer and an aromatic polyene is carried out by using a single-site coordination polymerization catalyst to synthesize an olefin/aromatic vinyl compound/aromatic polyene copolymer, and then, in the anionic polymerization step, polymerization is carried out in the coexistence of such an olefin/aromatic vinyl compound/aromatic polyene copolymer and an anionic polymerizable vinyl compound monomer by using an anionic polymerization initiator.
机译:为了提供一种新型的交叉共聚物和树脂组合物,与常规的乙烯/芳族乙烯基化合物共聚物相比,其耐热性和相容性得到改善,并且具有低的结晶度,优异的柔软性,透明性和相容性,并具有类似于软氯乙烯树脂的机械性能,与常规的交联共聚物相比;制备交联共聚物的方法,其包括配位聚合步骤和随后的阴离子聚合步骤,其中在配位聚合步骤中,烯烃单体,芳族乙烯基化合物单体和芳族化合物的共聚通过使用单中心配位聚合催化剂来进行多烯的合成以合成烯烃/芳族乙烯基化合物/芳族多烯共聚物,然后在阴离子聚合步骤中,在这种烯烃/芳族乙烯基化合物的共存下进行聚合。 /芳族多烯共聚物和阴离子c。通过使用阴离子聚合引发剂的可聚合乙烯基化合物单体。

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