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Process for preparing nanoparticles of nickel monooxide of high catalytic activity

机译:具有高催化活性的一氧化镍纳米粒子的制备方法

摘要

The process for preparing nanoparticles of the nickel with high catalytic activity resides in the fact that the reaction an aqueous solution of a photochemically and / or radiochemically sensitive compound containing nickel ions with the addition of scavengers -OH radical which is preferably selected from the group consisting of aliphatic alcohols or polyvinyl alcohol, or salts of organic acids containing anion -COO.sup .-. n., irradiated by UV radiation or gamma radiation of energy greater than 1 MeV or by accelerated electrons with energy 1-6 MeV dose of 5-150 Gy to give a finely dispersed solid phase of nickel oxide, solid phase is separated by ultrafiltration and dried at 100 degC and then the heat treatment at 200 to 600 degC.
机译:制备具有高催化活性的镍纳米颗粒的方法在于以下事实:含有镍离子的光化学和/或放射化学敏感化合物的水溶液与添加的清除剂-OH自由基反应,该清除剂优选选自下组:脂族醇或聚乙烯醇,或含有阴离子-COO.-的有机酸的盐。 n。通过大于1 MeV的能量的UV辐射或γ辐射或以1-6 MeV的能量5-150 Gy的加速电子辐照,得到细分散的氧化镍固相,通过超滤分离固相并在100℃下干燥,然后在200至600℃下进行热处理。

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