alpha-Arylation of oxindoles using recyclable metal oxide ferrite nanoparticles: Comparison between the catalytic activities of nickel, cobalt and copper ferrite nanoparticles

摘要

Three different spinel metal oxide catalytic systems including NiFe2O4, CuFe2O4 and CoFe2O4 were synthesized using co-precipitation technique and their catalytic activities were compared to each other in alpha-arylation of oxindole derivatives under the optimized reaction conditions. Both nickel ferrite and copper ferrite magnetic nanoparticles show approximately the same behavior in these reactions but cobalt ferrite ones indicate slightly different properties and were not as good as the other two catalysts. These superparamagnetic catalysts allowed that et-arylation of different types of oxindoles will occur in high yields under mild conditions and at very short times. (C) 2015 Elsevier B.V. All rights reserved.