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METHOD FOR PRODUCING A FREE ACID FROM THE SALT THEREOF.

机译:从其盐中产生游离酸的方法。

摘要

The invention relates to an improved method for releasing an organic acid, preferably a carbon, sulfone or phosphone acid, particularly an alpha or beta hydroxycarbon acid, from the ammonia salt thereof by releasing and removing ammoniac and simultaneous extraction of the released acid, having an amine as a suitable extraction means from the aqueous phase. This method corresponds to a reactive extraction. The reactive extraction of an organic acid from the aqueous ammonia salt solution thereof can be significantly improved by the use of a strip medium or carrier gas, such as nitrogen, air, water vapor or inert gases such as argon. The released ammoniac is removed from the aqueous solution by the continuous gas flow and can be resupplied into a production process. The free acid can be obtained by a method such as distillation, rectification, crystallization, reextraction, chromatography, adsorption or by a membrane method from the extraction means.
机译:本发明涉及一种改进的方法,该方法通过释放和除去氨气并同时萃取所释放的酸,从而从其氨盐中释放有机酸,优选碳,砜或膦酸,特别是α或β羟基碳酸。胺作为从水相中提取的合适方法。该方法对应于反应萃取。通过使用汽提介质或载气,例如氮气,空气,水蒸气或惰性气体,例如氩气,可以显着改善从氨盐水溶液中有机酸的反应性萃取。通过连续的气流将释放出的氨从水溶液中去除,并可以重新供应到生产过程中。游离酸可以通过例如蒸馏,精馏,结晶,再萃取,色谱法,吸附法或通过膜法从提取装置中获得。

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